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Unusual set of anomalies in the lattice dynamics of lawsonite near its phase transitions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F22%3A00569211" target="_blank" >RIV/68378271:_____/22:00569211 - isvavai.cz</a>

  • Result on the web

    <a href="https://ieeexplore.ieee.org/document/9895469" target="_blank" >https://ieeexplore.ieee.org/document/9895469</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1109/IRMMW-THz50927.2022.9895469" target="_blank" >10.1109/IRMMW-THz50927.2022.9895469</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Unusual set of anomalies in the lattice dynamics of lawsonite near its phase transitions

  • Original language description

    Lawsonite is a water-containing mineral occurring in the Earth’s crust and mantle, exhibiting low-temperature ferroelectricity linked to water molecules. Using broad-band polarized electromagnetic spectroscopy, we studied the lattice dynamics of a single crystal between 1Hz and 20THz at temperatures from 20 to 500K. We identified three anomalies associated with the two phase transitions occurring at 270 and 124K—a critical GHz relaxation, a soft THz phonon, and an overdamped sub-THz excitation in the E∥a,E∥b and E∥c permittivity spectra, respectively. The fact that the soft mode is polarized perpendicularly to the ferroelectric axis is very unusual.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    <a href="/en/project/GA20-01527S" target="_blank" >GA20-01527S: Interactions among water molecules localized in crystals tending to their orientational ordering</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz) /47./

  • ISBN

    978-1-7281-9427-1

  • ISSN

    2162-2027

  • e-ISSN

  • Number of pages

    2

  • Pages from-to

    9895469

  • Publisher name

    IEEE

  • Place of publication

    New York

  • Event location

    Delft

  • Event date

    Aug 28, 2022

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article

    000865953000004