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Modifying the magnetoelectric coupling in TbMnO3 by low-level Fe3+ substitution

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00570777" target="_blank" >RIV/68378271:_____/23:00570777 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1103/PhysRevB.107.104410" target="_blank" >https://doi.org/10.1103/PhysRevB.107.104410</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1103/PhysRevB.107.104410" target="_blank" >10.1103/PhysRevB.107.104410</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Modifying the magnetoelectric coupling in TbMnO3 by low-level Fe3+ substitution

  • Original language description

    We report a comprehensive study of the low-level substitution of Mn3+ by Fe3+ effect on the static and dynamic magnetoelectric coupling in TbMn1−xFexO3 (x=0, 0.02, and 0.04). Low-lying electromagnon excitation is activated in the cycloidal modulated antiferromagnetic and ferroelectric phase in TbMnO3, while it is observed up to TN in the Fe-substituted compounds, pointing at different mechanisms for static and dynamic magnetoelectric coupling. A second electrically active excitation near 40 cm−1 is explained by means of Tb3+ crystal-field effects. This excitation is observed up to room temperature, and exhibits a remarkable 15 cm−1 downshift on cooling in Fe-substituted compounds. Both electromagnon and crystal-field excitations are found to be coupled to the polar phonons with frequencies up to 250 cm−1. The anomalies in the T dependence of magnetic susceptibility above TN are well accounted for by spin-phonon coupling and crystal-field excitation, coupled to oxygen motions.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Review B

  • ISSN

    2469-9950

  • e-ISSN

    2469-9969

  • Volume of the periodical

    107

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    13

  • Pages from-to

    104410

  • UT code for WoS article

    000974419900001

  • EID of the result in the Scopus database

    2-s2.0-85150864856