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Below the urbach edge: solar cell loss analysis based on full external quantum efficiency spectra

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00574647" target="_blank" >RIV/68378271:_____/23:00574647 - isvavai.cz</a>

  • Alternative codes found

    RIV/68407700:21230/23:00367099 RIV/00216208:11320/23:10472957

  • Result on the web

    <a href="https://hdl.handle.net/11104/0346917" target="_blank" >https://hdl.handle.net/11104/0346917</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acsenergylett.3c00951" target="_blank" >10.1021/acsenergylett.3c00951</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Below the urbach edge: solar cell loss analysis based on full external quantum efficiency spectra

  • Original language description

    We suggest a new solar cell loss analysis by using the external quantum efficiency (EQE) measured with sufficiently high sensitivity to also account for defects. Unlike common radiative-limit methods, where the impact of deep defects is ignored by exponential extrapolation of the Urbach absorption edge, our loss analysis considers the full EQE including states below the Urbach edge and uses corrections for band-filling and light trapping. We validate this new metric on a whole range of photovoltaic materials and verify its accuracy by electrical simulations. Any deviations between this newly established metric and experimental open circuit voltage are due to the presence of spatially localized defects and are explained as violations of the assumption of flat quasi-Fermi levels through the device.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10306 - Optics (including laser optics and quantum optics)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS ENERGY LETTERS

  • ISSN

    2380-8195

  • e-ISSN

    2380-8195

  • Volume of the periodical

    8

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

    3221-3227

  • UT code for WoS article

    001021459800001

  • EID of the result in the Scopus database

    2-s2.0-85164932646