Generating antiaromaticity in polycyclic conjugated hydrocarbons by thermally selective skeletal rearrangements at interfaces
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00575505" target="_blank" >RIV/68378271:_____/23:00575505 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15640/23:73621323
Result on the web
<a href="https://doi.org/10.1038/s44160-023-00390-8" target="_blank" >https://doi.org/10.1038/s44160-023-00390-8</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1038/s44160-023-00390-8" target="_blank" >10.1038/s44160-023-00390-8</a>
Alternative languages
Result language
angličtina
Original language name
Generating antiaromaticity in polycyclic conjugated hydrocarbons by thermally selective skeletal rearrangements at interfaces
Original language description
Antiaromatic polycyclic conjugated hydrocarbons (PCHs) are attractive research targets because of their interesting structural, electronic and magnetic properties. Unlike aromatic compounds, the synthesis of antiaromatic PCHs is challenging because of their high reactivity and lack of stability, which stems from the small energy gap between their highest occupied and lowest unoccupied molecular orbitals. Here we describe a strategy for the introduction of antiaromatic units in PCHs via thermally selective intra- and intermolecular ring-rearrangement reactions of dibromomethylene-functionalized molecular precursors upon sublimation on a hot Au(111) metal surface, not available in solution chemistry.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
<a href="/en/project/GX20-13692X" target="_blank" >GX20-13692X: 1D molecular chains on surfaces</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Nature Synthesis
ISSN
2731-0582
e-ISSN
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Volume of the periodical
2
Issue of the periodical within the volume
12
Country of publishing house
GB - UNITED KINGDOM
Number of pages
12
Pages from-to
1159-1170
UT code for WoS article
001124810900007
EID of the result in the Scopus database
2-s2.0-85170355604