Oxazoline derivatives exhibiting chiral liquid crystalline mesophases
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00583489" target="_blank" >RIV/68378271:_____/23:00583489 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0351453" target="_blank" >https://hdl.handle.net/11104/0351453</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/02678292.2023.2252388" target="_blank" >10.1080/02678292.2023.2252388</a>
Alternative languages
Result language
angličtina
Original language name
Oxazoline derivatives exhibiting chiral liquid crystalline mesophases
Original language description
We have designed new chiral mesogens, OXm/n, containing an oxazoline chiral motif derived from natural L-serine amino acid. Our effort was concentrated on the evaluation of the synthetic accessibility of these new compounds and preserving their optical purity, which was determined using chiral high-performance liquid chromatography. We established materials mesomorphic properties and confirmed the phase identification by X-ray scattering studies. Depending on the ratio between the terminal alkyl chain lengths, the studied materials exhibited various smectic mesophases. The derivatives OXm/n with conformationally rigid oxazoline chiral moiety were compared with the structurally similar smectogens, ZLm/n, having a flexible (S)-lactate chiral unit, in order to investigate the effect of rigidisation of the chiral unit on the mesomorphic properties.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
<a href="/en/project/GA22-16499S" target="_blank" >GA22-16499S: Chirality as a tool for controlling photoresponsiveness of supramolecular arrangements</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Liquid Crystals
ISSN
0267-8292
e-ISSN
1366-5855
Volume of the periodical
50
Issue of the periodical within the volume
13-14
Country of publishing house
GB - UNITED KINGDOM
Number of pages
11
Pages from-to
2360-2370
UT code for WoS article
001061820000001
EID of the result in the Scopus database
2-s2.0-85169812244