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Hematite α-Fe2O3(0001) in top and side view: resolving long-standing controversies about its surface structure

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00583874" target="_blank" >RIV/68378271:_____/23:00583874 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/23:10477102

  • Result on the web

    <a href="https://hdl.handle.net/11104/0351870" target="_blank" >https://hdl.handle.net/11104/0351870</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/admi.202300602" target="_blank" >10.1002/admi.202300602</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Hematite α-Fe2O3(0001) in top and side view: resolving long-standing controversies about its surface structure

  • Original language description

    The atomic-scale structure of the hematite surface remains controversial despite decades of study, partly because it depends on sample history as well as the preparation conditions. Here, a comprehensive study is performed using an arsenal of surface techniques (non-contact atomic force microscopy, scanning tunneling microscopy, low-energy electron diffraction, and X-ray photoemission spectroscopy) complemented by analyses of the near surface region by high-resolution transmission electron microscopy and electron energy loss spectroscopy. The results show that the so-called “bi-phase” termination forms even under highly oxidizing conditions, a (1 × 1) surface is only observed in the presence of impurities. Furthermore, it is shown that the biphase is actually a continuous layer distorted due to a mismatch with the subsurface layers, and thus not the proposed mixture of FeO(111) and α-Fe2O3(0001) phases.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2023

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Advanced Materials Interfaces

  • ISSN

    2196-7350

  • e-ISSN

    2196-7350

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    32

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    2300602

  • UT code for WoS article

    001159240100001

  • EID of the result in the Scopus database

    2-s2.0-85168394306