Neocuproine/nitrato complexes of Ni(II). Neutral and cationic species including salts with TCNQ: Preparation, chemical and spectroscopic properties and comparative structural chemistry

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F24%3A00578773" target="_blank" >RIV/68378271:_____/24:00578773 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0347688" target="_blank" >https://hdl.handle.net/11104/0347688</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2023.136746" target="_blank" >10.1016/j.molstruc.2023.136746</a>

Result language
angličtina
Original language name
Neocuproine/nitrato complexes of Ni(II). Neutral and cationic species including salts with TCNQ: Preparation, chemical and spectroscopic properties and comparative structural chemistry
Original language description
The cationic complex [Ni(neoc)2(NO3)]+ with NO3- (1), TCNQ- (3), or (TCNQ-TCNQ)2- (4) as counterions, and the neutral complex [Ni(neoc)([NO3]- -κ1O)([NO3]- -κ2O,O´)(H2O)] (2) can be obtained from different reactions involving Ni(II), neoc, NO3- and TCNQ. The molecular and extended crystal structure of compound 2, which displays two different coordination modes for NO3- , are compared to those of the analogous Mn, Fe and Co compounds, revealing a correlation between the coordination geometry of the nominally monodentate nitrato ligand and the covalent radius of the central metal atom. Despite the differences in molecular geometry, the extended structures of the Ni (2) and Mn compounds are similar to each other but different from those of the Fe and Co complexes, which are similar to each other.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
<a href="/en/project/LM2023051" target="_blank" >LM2023051: Research infrastructure CzechNanoLab</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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