On-surface synthesis of a radical 2D supramolecular organic framework

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F24%3A00585738" target="_blank" >RIV/68378271:_____/24:00585738 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15640/24:73626130 RIV/61989592:15310/24:73626130 RIV/68407700:21340/24:00372225
Result on the web
<a href="https://hdl.handle.net/11104/0353455" target="_blank" >https://hdl.handle.net/11104/0353455</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jacs.3c13702" target="_blank" >10.1021/jacs.3c13702</a>

Result language
angličtina
Original language name
On-surface synthesis of a radical 2D supramolecular organic framework
Original language description
Here, we report the on-surface synthesis of a purely organic supramolecular radical framework on Au(111), by combining supramolecular and on-surface chemistry. We employ a tripodal precursor, functionalized with 7-azaindole groups that, catalyzed by a single gold atom on the surface, forms a radical molecular product constituted by a π-extended fluoradene-based radical core. The radical products self-assemble through hydrogen bonding, leading to extended 2D domains ordered in a Kagome-honeycomb lattice. This approach demonstrates the potential of on-surface synthesis for developing 2D supramolecular radical organic chemistry.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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