On-surface covalent synthesis of carbon nanomaterials by harnessing carbon gem-polyhalides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F24%3A00599564" target="_blank" >RIV/68378271:_____/24:00599564 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1002/adma.202402467" target="_blank" >https://doi.org/10.1002/adma.202402467</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adma.202402467" target="_blank" >10.1002/adma.202402467</a>
Alternative languages
Result language
angličtina
Original language name
On-surface covalent synthesis of carbon nanomaterials by harnessing carbon gem-polyhalides
Original language description
The design of innovative carbon-based nanostructures stands at the forefront of both chemistry and materials science. In this context, π-conjugated compounds are of great interest due to their impact in a variety of fields, including optoelectronics, spintronics, energy storage, sensing and catalysis. Despite extensive research efforts, substantial knowledge gaps persist in the synthesis and characterization of new π-conjugated compounds with potential implications for science and technology. On-surface synthesis has emerged as a powerful discipline to overcome limitations associated with conventional solution chemistry methods, offering advanced tools to characterize the resulting nanomaterials. This review specifically highlights recent achievements in the utilization of molecular precursors incorporating carbon geminal (gem)-polyhalides as functional groups to guide the formation of π-conjugated 0D species, as well as 1D, quasi-1D π-conjugated polymers, and 2D nanoarchitectures. By delving into reaction pathways, novel structural designs, and the electronic, magnetic, and topological features of the resulting products, the review provides fundamental insights for a new generation of π-conjugated materials.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Advanced Materials
ISSN
0935-9648
e-ISSN
1521-4095
Volume of the periodical
36
Issue of the periodical within the volume
33
Country of publishing house
DE - GERMANY
Number of pages
17
Pages from-to
2402467
UT code for WoS article
001251091800001
EID of the result in the Scopus database
2-s2.0-85196391121