Magnetic ground state discrimination of a polyradical nanographene using nickelocene-functionalized tips
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F25%3A00640822" target="_blank" >RIV/68378271:_____/25:00640822 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0373441" target="_blank" >https://hdl.handle.net/11104/0373441</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jacs.5c11722" target="_blank" >10.1021/jacs.5c11722</a>
Alternative languages
Result language
angličtina
Original language name
Magnetic ground state discrimination of a polyradical nanographene using nickelocene-functionalized tips
Original language description
Molecular magnets are a promising class of materials with exciting properties and applications. However, a profound understanding and application of such materials depend on the accurate detection of their electronic and magnetic properties. Despite the availability of experimental techniques that can sense the magnetic signal, the exact determination of the spin ground states and spatial distribution of the exchange interaction of strongly correlated single-molecule magnets remain challenging. Here, we demonstrate that scanning probe microscopy with a nickelocene-functionalized probe can distinguish between nearly degenerate multireference ground states of single-molecule π-magnets and map their spatial distribution of the exchange interaction. This method expands the already outstanding imaging capabilities of scanning probe microscopy for characterizing the chemical and electronic structures of individual molecules, paving the way for the study of strongly correlated molecular magnets with unprecedented spatial resolution.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the American Chemical Society
ISSN
0002-7863
e-ISSN
1520-5126
Volume of the periodical
147
Issue of the periodical within the volume
43
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
39072-39079
UT code for WoS article
001596558400001
EID of the result in the Scopus database
2-s2.0-105020196238