Phosphate-based geopolymer: Influence of municipal solid waste fly ash introduction on structure and compressive strength
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378297%3A_____%2F23%3A00570921" target="_blank" >RIV/68378297:_____/23:00570921 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.ceramint.2023.04.042" target="_blank" >https://doi.org/10.1016/j.ceramint.2023.04.042</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ceramint.2023.04.042" target="_blank" >10.1016/j.ceramint.2023.04.042</a>
Alternative languages
Result language
angličtina
Original language name
Phosphate-based geopolymer: Influence of municipal solid waste fly ash introduction on structure and compressive strength
Original language description
Materials resulting from incorporation of solid waste incineration fly ash into phosphate-based geopolymers, to partially replace metakaolin (up to 50% wt), were studied. X-ray diffraction, scanning electron microscopy, solidstate nuclear magnetic resonance spectroscopy and infrared spectroscopy were adopted to describe the mineralogical changes and the structural modifications of the geopolymer networks which impacted on the mechanical performance (compressive strength) of the materials. The results indicated that fly ash displays a different reactivity compared with metakaolin, behaving preferentially as a source of alkali that compete with the aluminosilicate metakaolin fraction by precipitating crystalline and amorphous phosphates. At 10 wt% of metakaolin substitution with fly ash, the extent and reticulation of the amorphous geopolymer matrix is preserved, and the mechanical properties are retained. At higher waste content (30–50% wt), the fast kinetics of the acid-base reactions involving the fly ash reactive phases prevail over the metakaolin dealumination, and the nature of the material shifts to an alkali-phosphate cement/phosphate-geopolymer composite. This behaviour, together with the development of porosity and presence of low-strength phases in the ash, led to a decline in the mechanical performance with increasing amount of substitution. All in all, this work provides fundamental information in the direction of a sustainable employment of phosphate-based geopolymers, which is limited by the relatively high cost of both metakaolin and phosphoric acid. Moreover, it indicates a recycling opportunity for this type of fly ash.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20501 - Materials engineering
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Ceramics International
ISSN
0272-8842
e-ISSN
1873-3956
Volume of the periodical
49
Issue of the periodical within the volume
13
Country of publishing house
GB - UNITED KINGDOM
Number of pages
11
Pages from-to
22149-22159
UT code for WoS article
001013288300001
EID of the result in the Scopus database
2-s2.0-85152418728