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The time lag in surface diffusion evaluated for the BET and BSB isotherms

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21110%2F21%3A00349654" target="_blank" >RIV/68407700:21110/21:00349654 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1063/5.0047728" target="_blank" >http://dx.doi.org/10.1063/5.0047728</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1063/5.0047728" target="_blank" >10.1063/5.0047728</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    The time lag in surface diffusion evaluated for the BET and BSB isotherms

  • Original language description

    One of the experimental methods to determine the coefficient of surface diffusion of species migrating in a porous material uses the measurement of the time lag. It represents the time required for the species to spend their life within the material when permeating through it. Describing the mass transport by a suitable transport model, the time lag can be expressed in terms of integrals whose evaluation depends on the adsorption isotherm of the studied species in the material. For porous building materials, the BET (Brunauer–Emmett–Teller) and BSB (Brunauer–Skalny–Bodor) model isotherms are usually very good approximations to the measured isotherms at low and medium concentrations. In this paper we derive a formula for the time lag for both these model isotherms. The formula can be readily applied in the analysis of experimental data, whereas the general expression involving integrals is much less straightforward to employ, being usually evaluated numerically for fixed values of parameters. The sensitivity of the time lag formula to the surface diffusivity is illustrated for an example of a porous brick with a water adsorption isotherm known from previous experiments.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)

Result continuities

  • Project

    <a href="/en/project/FV40007" target="_blank" >FV40007: Innovation of the production technology of lightened brick body for thin-walled brick blocks</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    AIP Conference Proceedings 2343

  • ISBN

    9780735440883

  • ISSN

    0094-243X

  • e-ISSN

  • Number of pages

    4

  • Pages from-to

  • Publisher name

    American Institute of Physics

  • Place of publication

    Melville, New York

  • Event location

    Heraklion

  • Event date

    Apr 29, 2020

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article