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Linear and Nonlinear Optical Susceptibilities and the Hyperpolarizability of Borate LiBaB9O15 Single-Crystal: Theory and Experiment

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21220%2F13%3A00216343" target="_blank" >RIV/68407700:21220/13:00216343 - isvavai.cz</a>

  • Alternative codes found

    RIV/60076658:12520/13:43885175

  • Result on the web

    <a href="http://dx.doi.org/10.1021/jp4077905" target="_blank" >http://dx.doi.org/10.1021/jp4077905</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/jp4077905" target="_blank" >10.1021/jp4077905</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Linear and Nonlinear Optical Susceptibilities and the Hyperpolarizability of Borate LiBaB9O15 Single-Crystal: Theory and Experiment

  • Original language description

    The single-crystal borate LiBaB9O15 was synthesized by a high-temperature solution reaction and structurally determined by the single-crystal X-ray diffraction technique. It crystallizes in the noncentrosymmetric space group R3c and features a three-dimensional infinity3[B9O15]3? anionic framework, with infinite channels in which the Li+ and Ba2+ cations are located. The linear optical properties were investigated experimentally in terms of the absorption spectrum, which reveals an optical gap of 5.17 eV. In addition we have calculated the linear optical properties using state-of-the-art all-electron full potential linearized augmented plane wave method. The nonlinear optical susceptibilities, namely, the second harmonic generation and the hyperpolarizability of the single-crystal borate LiBaB9O15 are calculated and evaluated at a static limit and at ? = 1064 nm. The calculation shows there exists three second-order nonlinear optical susceptiblities tensors components. We present measu

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ED2.1.00%2F01.0024" target="_blank" >ED2.1.00/01.0024: South Bohemian Research Center of Aquaculture and Biodiversity of Hydrocenoses</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    The Journal of Physical Chemistry B

  • ISSN

    1520-6106

  • e-ISSN

  • Volume of the periodical

    2013

  • Issue of the periodical within the volume

    117

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    10

  • Pages from-to

    14141-14150

  • UT code for WoS article

    000327111200023

  • EID of the result in the Scopus database