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Tribological and micromechanical performance of hard yet tough TiSiN/ WN coatings: An experimental analysis of multilayer effects

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21220%2F25%3A00390133" target="_blank" >RIV/68407700:21220/25:00390133 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1016/j.ijrmhm.2025.107212" target="_blank" >https://doi.org/10.1016/j.ijrmhm.2025.107212</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.ijrmhm.2025.107212" target="_blank" >10.1016/j.ijrmhm.2025.107212</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Tribological and micromechanical performance of hard yet tough TiSiN/ WN coatings: An experimental analysis of multilayer effects

  • Original language description

    Hard nitride coatings have the potential to serve as protective layers for cutting tools due to their excellent mechanical properties and wear resistance. To improve their mechanical, tribological, and high-temperature oxidation characteristics, the structural design of the coating is crucial. This study explores the micro-mechanical and tribological properties of multilayer WN/TiSiN and monolayer WN and TiSiN coatings prepared using magnetron sputtering. We compare the adhesion strength, wear resistance, and failure mechanisms in these systems. The multilayer WN/TiSiN coating demonstrates superior adhesion strength and crack resistance. Scratch tests confirm cohesive-adhesive failure modes with spallation localized to interfacial zones, allowing the coating to withstand extra loading. Tribological analysis revealed distinct wear mechanisms among the coatings. While the WN coating had the lowest wear rate (1.3 x 10-6 mm3/Nm), its poor adhesion and susceptibility to failure under stress reduced its reliability. Conversely, the TiSiN coating exhibits higher wear rates (2.4 x 10-6 mm3/ Nm) but maintains stable performance through oxide film formation. On the other hand, the WN/TiSiN multi-layer coating combined the strengths of both monolithic layers with moderate wear rates (1.7 x 10-6 mm3/Nm) and a low coefficient of friction (0.5). Raman spectroscopy confirmed the formation of protective oxide films, such as WO3 and TiO2, contributing to reduced wear and enhanced stability.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20506 - Coating and films

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    International Journal of Refractory Metals and Hard Materials

  • ISSN

    0263-4368

  • e-ISSN

    2213-3917

  • Volume of the periodical

    131

  • Issue of the periodical within the volume

    September

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    14

  • Pages from-to

    1-14

  • UT code for WoS article

    001485694800003

  • EID of the result in the Scopus database

    2-s2.0-105003814852