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Enhancing the irradiation resistance of Cr coating via periodic insertion of nanochannel CrAlSiN layers that act as elastic unsaturated "sponges"

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21230%2F25%3A00383319" target="_blank" >RIV/68407700:21230/25:00383319 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1016/j.corsci.2025.112742" target="_blank" >https://doi.org/10.1016/j.corsci.2025.112742</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.corsci.2025.112742" target="_blank" >10.1016/j.corsci.2025.112742</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Enhancing the irradiation resistance of Cr coating via periodic insertion of nanochannel CrAlSiN layers that act as elastic unsaturated "sponges"

  • Original language description

    Cr-based coatings, as protective coatings of Zr-alloy fuel claddings, inevitably suffer from irradiation damage under actual nuclear operating conditions. Here, Cr/CrAlSiN multilayer coatings were deposited on Zircaloy substrates by magnetron sputtering, followed by the evaluation of irradiation resistance using Fe ions. The insertion of nanochannel-CrAlSiN layers refined the columns/grains in Cr layers and increased the interface density, contributing to the greatly enhanced irradiation tolerance and mechanical properties. A low average swelling rate of Cr layers was estimated to be similar to 0.015 %/dpa after the irradiation of Fe ions at 400 degrees C. Moreover, the coating became compacted with strengthening columnar boundaries after low-dose irradiation (similar to 0.8 dpa). Both nanoindentation and micropillar compression test showed the transformation of the deformation mechanism for the multilayer coating, as the irradiated samples relieved stress mainly depending on the plastic deformation under loading, while many cracks formed in the as-deposited ones. Furthermore, in 1200 degrees C steam, a significantly thinner and denser oxide scale formed on the irradiated Cr/CrAlSiN coating, indicative of improved oxidation resistance. The mechanism of radiation-decelerated oxidation was briefly discussed.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20506 - Coating and films

Result continuities

  • Project

    <a href="/en/project/EH22_008%2F0004590" target="_blank" >EH22_008/0004590: Robotics and advanced industrial production</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2025

  • Confidentiality

    C - Předmět řešení projektu podléhá obchodnímu tajemství (§ 504 Občanského zákoníku), ale název projektu, cíle projektu a u ukončeného nebo zastaveného projektu zhodnocení výsledku řešení projektu (údaje P03, P04, P15, P19, P29, PN8) dodané do CEP, jsou upraveny tak, aby byly zveřejnitelné.

Data specific for result type

  • Name of the periodical

    Corrosion Science

  • ISSN

    0010-938X

  • e-ISSN

    1879-0496

  • Volume of the periodical

    246

  • Issue of the periodical within the volume

    April

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    13

  • Pages from-to

  • UT code for WoS article

    001425143100001

  • EID of the result in the Scopus database

    2-s2.0-85216898445