Synthesis of Novel BTPhen-functionalized Silica-coated Magnetic Nanoparticles for Separating Trivalent Actinides and Lanthanides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F17%3A00315805" target="_blank" >RIV/68407700:21340/17:00315805 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1055/s-0036-1590865" target="_blank" >http://dx.doi.org/10.1055/s-0036-1590865</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1055/s-0036-1590865" target="_blank" >10.1055/s-0036-1590865</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis of Novel BTPhen-functionalized Silica-coated Magnetic Nanoparticles for Separating Trivalent Actinides and Lanthanides
Original language description
BTPhen [bis-(1,2,4-triazin-3-yl)-1,10-phenanthroline] functionalized magnetic nanoparticles (MNPs), which selectively extracts Am(III) over Eu(III) from 0.1 – 4 M HNO3 with fast kinetics and separation factors > 20 have been synthesized. These MNPs also show a small but significant selectivity for Am(III) over Cm(III) with a separation factor of around 3 in 0.1 M HNO3. We report also the synthesis of the BTPhen and related ligands via an improved synthetic route by-passing the problematic benzylic oxidation with stoichiometric SeO2.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
—
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Synlett
ISSN
0936-5214
e-ISSN
1437-2096
Volume of the periodical
28
Issue of the periodical within the volume
20
Country of publishing house
US - UNITED STATES
Number of pages
5
Pages from-to
2795-2799
UT code for WoS article
000418271100014
EID of the result in the Scopus database
2-s2.0-85027974996