Separation of Am(III), Cm(III) and Eu(III) by electro-spun polystyrene-immobilized CyMe4-BTPhen

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F18%3A00325461" target="_blank" >RIV/68407700:21340/18:00325461 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.tet.2018.04.037" target="_blank" >http://dx.doi.org/10.1016/j.tet.2018.04.037</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.tet.2018.04.037" target="_blank" >10.1016/j.tet.2018.04.037</a>

Result language

angličtina

Original language name

Separation of Am(III), Cm(III) and Eu(III) by electro-spun polystyrene-immobilized CyMe4-BTPhen

Original language description

The synthesis of a novel 5-(4-vinylphenyl)-CyMe4-BTPhen actinide selective ligand using selenium free synthetic procedures is reported. For the first time, we report the electrospinning of this actinide selective ligand into a polystyrene fiber and investigate its selective removal of Am(III) from Eu(III) and Am(III) from Cm(III). At 4 M HNO3, the resulting fibrous solid extractant produced separation factors of SFAm/Eu ~ 57 and a small, but significant separation of SFAm/Cm ~ 2.9.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10400 - Chemical sciences

Project

—

Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2018

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Tetrahedron

ISSN

0040-4020

e-ISSN

—

Volume of the periodical

74

Issue of the periodical within the volume

38

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

5

Pages from-to

5258-5262

UT code for WoS article

000445305400038

EID of the result in the Scopus database

2-s2.0-85047262822