Comparison of Sr Transport in Compacted Homoionous Na and Ca Bentonite Using a Planar Source Method Evaluated at Ideal and Non-Ideal Boundary Condition

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F21%3A00353026" target="_blank" >RIV/68407700:21340/21:00353026 - isvavai.cz</a>

Result on the web

<a href="https://doi.org/10.3390/w13111520" target="_blank" >https://doi.org/10.3390/w13111520</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/w13111520" target="_blank" >10.3390/w13111520</a>

Result language

angličtina

Original language name

Comparison of Sr Transport in Compacted Homoionous Na and Ca Bentonite Using a Planar Source Method Evaluated at Ideal and Non-Ideal Boundary Condition

Original language description

With the aim to determine the influence of dominant interlayer cation on the sorption and diffusion properties of bentonite, diffusion experiments with Sr on the compacted homoionous Ca- and Na-forms of Czech natural Mg/Ca bentonite using the planar source method were performed. The bentonite was compacted to 1400 kg.m-3, and diffusion experiments lasted 1, 3 or 5 days. Two methods of apparent diffusion coefficient Da determination based on the ana-lytical solution of diffusion equation for ideal boundary conditions in a linear form were compared and applied. The determined Da value for Ca-bentonite was 1.36 times higher than that for Na-bentonite sample. Values of Kd were determined in independent batch sorption experiments and were extrapolated for the conditions of compacted bentonite. In spite of this treatment, the use of Kd values determined by batch sorption experiments on a loose material for the determination of effective diffusion coefficient De values from planar source diffusion experiments proved to be inconsistent with the standard Fickian description of diffusion taking into account only the pore diffusion in compacted bentonite. Discrepancies between Kd and De values were measured in independent experiments, and those that resulted from the evaluation of planar source diffusion experiments could be well explained by the phenomenon of surface diffusion. The obtained values of surface diffusion coefficients Ds were similar for both studied systems, and the predicted value of total effective diffusion coefficient De(tot) describing Sr transport in the Na-bentonite was four times higher than in the Ca-bentonite.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10402 - Inorganic and nuclear chemistry

Project

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Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2021

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Water

ISSN

2073-4441

e-ISSN

2073-4441

Volume of the periodical

13

Issue of the periodical within the volume

11

Country of publishing house

CH - SWITZERLAND

Number of pages

14

Pages from-to

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UT code for WoS article

000660825100001

EID of the result in the Scopus database

2-s2.0-85107849395