Gallium and germanium static and kinetic sorption and desorption studies on cerium dioxide nanoparticles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F23%3A00369246" target="_blank" >RIV/68407700:21340/23:00369246 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1007/s42452-023-05561-y" target="_blank" >https://doi.org/10.1007/s42452-023-05561-y</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s42452-023-05561-y" target="_blank" >10.1007/s42452-023-05561-y</a>
Alternative languages
Result language
angličtina
Original language name
Gallium and germanium static and kinetic sorption and desorption studies on cerium dioxide nanoparticles
Original language description
Positron-emitting 68Ga has become an integral part of nuclear medicine. It is a radionuclide obtained from 68Ge/68Ga radionuclide generators. Apart from other qualities, it is a feature that have caused its growing popularity in medical practice. Nevertheless, the increasing demand for 68Ga supply results in the need of new and improved separation systems to obtain it. Hydrous oxides such as titanium or zirconium dioxide are usually the preferred separation materials, but other oxidic materials are under study. Thorough testing of the sorption behaviour is often overlooked in these studies, though it is indispensable for the applicability and suitability assessment. This work is focused on the sorption behaviour description of cerium dioxide prepared by calcination of ceric nitrate. Both batch and kinetic sorption experiments were conducted. Such a thorough study has never been carried out for this material. In batch experiments, the optimal conditions for separation of 68Ga and 68Ge were found. Kinetic experimental data were used for mathematical modelling. Six kinetic models derived from various rate-controlling processes were used and their applicability was demonstrated. The diffusion in an inert layer is the rate-controlling process of both gallium and germanium sorption and desorption. This model description of sorption kinetics will further enable us to optimise the sorption and desorption processes numerically. Thus far, it was found out that the prepared cerium dioxide can quantitatively adsorb germanium in very short time of 10 min from 1mM hydrochloric acid and the most convenient medium for 68Ge and 68Ga separation is 0.1 M hydrochloric acid.
Czech name
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Czech description
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Classification
Type
J<sub>SC</sub> - Article in a specialist periodical, which is included in the SCOPUS database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/TJ01000334" target="_blank" >TJ01000334: Novel composite materials for medical radionuclides separation</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
SN Applied Sciences
ISSN
2523-3971
e-ISSN
2523-3971
Volume of the periodical
2023
Issue of the periodical within the volume
11
Country of publishing house
CH - SWITZERLAND
Number of pages
10
Pages from-to
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UT code for WoS article
001101837500003
EID of the result in the Scopus database
2-s2.0-85175978366