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Adsorption of nerve agent simulants onto vermiculite structure: Experiments and modelling

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70565813%3A_____%2F19%3AN0000013" target="_blank" >RIV/70565813:_____/19:N0000013 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/20:10422605 RIV/61989100:27360/20:10242343 RIV/61989100:27640/20:10242343 RIV/61989100:27730/20:10242343

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/abs/pii/S0304389419309550?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/abs/pii/S0304389419309550?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jhazmat.2019.121001" target="_blank" >10.1016/j.jhazmat.2019.121001</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Adsorption of nerve agent simulants onto vermiculite structure: Experiments and modelling

  • Original language description

    Chemical warfare agents are still a threat to humanity despite the existence of a ban on their production and use. There are many new materials that have been experimentally verified to be effective in degrading and elim- inating various chemical warfare agents; however, clay minerals still remain very effective, environmentally friendly and not expensive. Vermiculites modified with hexadecylpyridinium, hexadecyltrimethylammonium and tetramethylammonium cations were used for static sorption of vapours of two simulants of nerve agents: dimethyl methyl phosphonate and diethyl ethyl phosphonate. The materials before and after sorption were characterized using infrared spectroscopy, X-ray diffraction and carbon phase analysis. The breakthrough time and capture of simulants were measured using dynamic sorption test. Molecular modelling was used to confirm the experimental results and provide a deeper insight into the structure of the materials and sorption processes.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Hazardous Materials

  • ISSN

    0304-3894

  • e-ISSN

    1873-3336

  • Volume of the periodical

    382

  • Issue of the periodical within the volume

    15.1.2020/Online:17.8.2019

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    9

  • Pages from-to

    nestrankovano

  • UT code for WoS article

    000501387100021

  • EID of the result in the Scopus database

    2-s2.0-85071081643