Unprecedented reactivity of 3-amino-1H,3H-quinoline-2,4-diones with urea: An efficient synthesis of 2,6-dihydro-imidazo[1,5-c]quinazoline-3,5-diones
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F03%3A63501409" target="_blank" >RIV/70883521:28110/03:63501409 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Unprecedented reactivity of 3-amino-1H,3H-quinoline-2,4-diones with urea: An efficient synthesis of 2,6-dihydro-imidazo[1,5-c]quinazoline-3,5-diones
Original language description
Substituted 3-amino-1H,3H-quinoline-2,4-diones react with urea in acetic acid to give novel 2,6-dihydro-imidazol[1,5-c]-quinazoline-3,5-diones in high yields. The same compounds were obtained, albeit with small yields, from 3-chloro-1H,3H-quinoline-2,4-diones and urea. In the proposed reaction mechanism, a molecular rearrangement of the primarily formed mono-substituted urea takes splace. The prepared 2,6-dihydro-imidazo[1,5-c]quinazoline-3,5-diones were characterized by their 1H, 13C, 15N NMR and IR spectra and atmospheric pressure chemical ionisation mass spectra.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
TETRAHEDRON
ISSN
0040-4020
e-ISSN
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Volume of the periodical
Neuveden
Issue of the periodical within the volume
59
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
1283-1288
UT code for WoS article
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EID of the result in the Scopus database
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