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NANOCOMPOSITES BASED ON STYRENE-ISOPRENE-STYRENE BLOCK COPOLYMERS AND COVALENTLY MODIFIED CARBON NANOTUBES

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F12%3A43866992" target="_blank" >RIV/70883521:28110/12:43866992 - isvavai.cz</a>

  • Alternative codes found

    RIV/70883521:28610/12:43866992

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    NANOCOMPOSITES BASED ON STYRENE-ISOPRENE-STYRENE BLOCK COPOLYMERS AND COVALENTLY MODIFIED CARBON NANOTUBES

  • Original language description

    Multiwall carbon nanotubes (MWCNT) were covalently modified in order to achieve better dispersion in a block copolymer matrix. Surface of MWCNT was modified either a) by polymerization of styrene from MWCNT surface (MWCNT-PS), or b) by covalent bonding of cholesteryl groups (MWCNT-chol). In both cases, MWCNT surface was first modified by 4-(2-hydroxyethyl)nitrobenzene to introduce hydroxyl groups onto MWCNT surface (MWCNT-OH). MWCNT-PS were prepared by reaction of MWCNT-OH with 2-bromopropionyl bromideand subsequent atom transfer radical polymerization of styrene from the surface of MWCNT by ATRP using CuBr/PMDETA as a catalytic system. MWCNT-chol were prepared by esterification of MWCNT-OH by reaction with cholesteryl chloroformate. The modified MWCNT were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravimetric analyses (TGA), and Fourier transmission infrared spectroscopy (FTIR). The composite films were prepared by casting of

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů