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The Influence of nucleating agents and process parameters on phase structure of isotactic polypropylene and its Copolymer with 3% ethylene

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28110%2F16%3A43874581" target="_blank" >RIV/70883521:28110/16:43874581 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    The Influence of nucleating agents and process parameters on phase structure of isotactic polypropylene and its Copolymer with 3% ethylene

  • Original language description

    The homopolymer of the isotactic polypropylene (iPP) and the random copolymer of the isotactic polypropyleneand 3% ethylene (iPPE) were used in this study. Isotactic polypropylene can be prepared in α, β and γ morphologicalphases depending on its crystallization conditions. The phase β content has a strong influence on mechanical,optical and thermal properties. The samples with nucleating agents (NA) α and β were used. Various processparameters were used to prepare melted samples: two thicknesses and three different cooling regimes. Wide-angleX-ray scattering (WAXD) and scanning electron microscopy (SEM) were used to investigate the phase structure.The results show that iPP without nucleation agents (4mm, <1oC /min) has the highest crystallinity (83.7%). Thesample of iPP with β-NA (4mm, <1oC /min) has the highest phase β (61.3%); the slower cooling regime and thehigher thickness increased the crystallinity (73.3%). iPPE with β-NA (0.4mm, 15oC /min) has the lower amount ofthe phase β (33.8%); the higher thickness and slower cooling regime decreased the amount of the phase β (7.1%)however the crystalline content of iPPE (63.7%) is increased.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Manufacturing Technology

  • ISSN

    1213-2489

  • e-ISSN

  • Volume of the periodical

    16

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    4

  • Pages from-to

    103-106

  • UT code for WoS article

  • EID of the result in the Scopus database

    2-s2.0-84976466913