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Influence of supercritical CO2 and initial melting temperature on crystallization of polypropylene/organoclay nanocomposite

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28140%2F12%3A43867821" target="_blank" >RIV/70883521:28140/12:43867821 - isvavai.cz</a>

  • Alternative codes found

    RIV/70883521:28110/12:43867821 RIV/70883521:28610/12:43867821 RIV/70883521:28150/12:43867821

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.polymertesting.2012.01.004" target="_blank" >http://dx.doi.org/10.1016/j.polymertesting.2012.01.004</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.polymertesting.2012.01.004" target="_blank" >10.1016/j.polymertesting.2012.01.004</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Influence of supercritical CO2 and initial melting temperature on crystallization of polypropylene/organoclay nanocomposite

  • Original language description

    Polypropylene (PP)/clay nanocomposite with maleic anhydride modified polypropylene (PP-MA) was prepared using a twin-screw extruder. The effect of supercritical carbon dioxide (scCO(2)) on mixing was investigated. Isothermal crystallization of the nanocomposites was investigated by differential scanning calorimetry (DSC) and also by optical microscopy as a function of initial melting temperature. Increasing initial melting temperature causes a gradual decrease in bulk crystallization kinetics, with theexception of the 240-260 degrees C temperature range for the system without CO2. Optical microscopy revealed a large number of small spherulites for the system without CO2 after initial melting at 250 degrees C. After 28 min initial induction period of crystallization many small spherulites appeared in the vicinity of large spherulites for the system with CO2, indicating the beginning of homogenous nucleation. X-ray diffraction (XRD) and direct observation of the samples after tensile te

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polymer Testing

  • ISSN

    0142-9418

  • e-ISSN

  • Volume of the periodical

    31

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    11

  • Pages from-to

    444-454

  • UT code for WoS article

    000302758100012

  • EID of the result in the Scopus database