Curing behavior and reaction kinetics of binder resins for 3D-printing investigated by dielectric analysis (DEA)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F16%3A43874637" target="_blank" >RIV/70883521:28610/16:43874637 - isvavai.cz</a>
Result on the web
<a href="http://aip.scitation.org/doi/abs/10.1063/1.4949649" target="_blank" >http://aip.scitation.org/doi/abs/10.1063/1.4949649</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1063/1.4949649" target="_blank" >10.1063/1.4949649</a>
Alternative languages
Result language
angličtina
Original language name
Curing behavior and reaction kinetics of binder resins for 3D-printing investigated by dielectric analysis (DEA)
Original language description
3D-Printing is an efficient method in the field of additive manufacturing. In order to optimize the properties of manufactured parts it is essential to adapt the curing behavior of the resin systems with respect to the requirements. Thus, effects of resin composition, e.g. due to different additives such as thickener and curing agents, on the curing behavior have to be known. As the resin transfers from a liquid to a solid glass the time dependent ion viscosity was measured using DEA with flat IDEX sensors. This allows for a sensitive measurement of resin changes as the ion viscosity changes two to four decades. The investigated resin systems are based on the monomers styrene and HEMA. To account for the effects of copolymerization in the calculation of the reaction kinetics it was assumed that the reaction can be considered as a homo-polymerization having a reaction order n?1. Then the measured ion viscosity curves are fitted with the solution of the reactions kinetics - the time dependent degree of conversion (DC-function) - for times exceeding the initiation phase representing the primary curing. The measured ion viscosity curves can nicely be fitted with the DC-function and the determined fit parameters distinguish distinctly between the investigated resin compositions.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
N - Vyzkumna aktivita podporovana z neverejnych zdroju
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Proceedings of PPS-30: The 30th International Conference of the Polymer Processing Society
ISBN
978-0-7354-1309-2
ISSN
0094-243X
e-ISSN
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Number of pages
4
Pages from-to
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Publisher name
American Institute of Physics
Place of publication
Melville
Event location
Ischia
Event date
Jun 19, 2016
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
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