Interface-engineered MoS2/C nanosheet heterostructure arrays for ultra-stable sodium-ion batteries
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F17%3A63517218" target="_blank" >RIV/70883521:28610/17:63517218 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ces.2017.09.007" target="_blank" >http://dx.doi.org/10.1016/j.ces.2017.09.007</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ces.2017.09.007" target="_blank" >10.1016/j.ces.2017.09.007</a>
Alternative languages
Result language
angličtina
Original language name
Interface-engineered MoS2/C nanosheet heterostructure arrays for ultra-stable sodium-ion batteries
Original language description
Development of ultra-stable high capacity electrodes is imperative for the widespread commercialization of sodium-ion batteries. Herein, we employed a micro-area etching and surface functionalization strategy to synthesize two-dimensional (2D) MoS2/C nanosheets with a well-defined heterointerface vertically anchored on a carbon cloth. The large MoS2/C nanosheet heterointerface and a high interlayer distance (0.99 nm) not only facilitated Na+ intercalation but also improved the diffusion kinetics of Na+ in the 2D interlayer space. A modulation of the cut-off voltage yielded a high specific capacity of 433 mAh g−1 at 0.2 A g−1 and 232 mAh g−1 at 10 A g−1 within the potential range of 0.4–3.0 V. These values are much higher than that of pure MoS2 nanosheet arrays (162 mAh g−1 at 10 A g−1). More importantly, during the first 1500 cycles, the capacity was maintained at ∼320 mAh g−1 at 1 A g−1, while after 10000 cycles, it became approximately ∼271 mAh g−1 at 3 A g−1. These are the best values ever reported for MoS2-based anode materials for SIBs. Furthermore, after being assembled into a flexible battery, it withstand repeated bending for over 200 times without any obvious capacity loss. Hence, this material is a promising electrode for future flexible batteries.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20201 - Electrical and electronic engineering
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Engineering Science
ISSN
0009-2509
e-ISSN
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Volume of the periodical
174
Issue of the periodical within the volume
Neuveden
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
104-111
UT code for WoS article
000413321000009
EID of the result in the Scopus database
2-s2.0-85029067498