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PVDF/PVDF-TRFE blends loaded with BaTiO3: from processing to performance testing

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F21%3A63559917" target="_blank" >RIV/70883521:28610/21:63559917 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216305:26220/21:PU147863

  • Result on the web

    <a href="http://dx.doi.org/10.37904/nanocon.2021.4327" target="_blank" >http://dx.doi.org/10.37904/nanocon.2021.4327</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.37904/nanocon.2021.4327" target="_blank" >10.37904/nanocon.2021.4327</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    PVDF/PVDF-TRFE blends loaded with BaTiO3: from processing to performance testing

  • Original language description

    Concerns surrounding the limited supply of fossil fuels have been the subject of much debate. As of promising solutions, polymers like poly(vinylidene fluoride) (PVDF) have gained attention due to their ability to generate electrical energy from the waste mechanical vibrations. The energy harvesting and vibration sensing potential of PVDF is however limited due to its low content of electroactive β-phase, which has to be increased by indirect post-processing. Recently, a synergistic effect was found in PVDF directly blended with its trifluoroethylene copolymer (PVDF-TrFE) due to strong interfacial polarization. In this study, we aim to further increment the piezoelectric performance of PVDF/PVDF-TrFE blends by incorporating a small amount of BaTiO3 nanocrystals via a facile and scalable processing route. The β-phase content was monitored using FTIR and XRD. Melt rheology experiments showed that co-blending of PVDF-TrFE as well as the addition of BaTiO3 slightly increased melt viscosity and complex modulus. Despite that, rheological data suggested that developed formulations can be processed by conventional techniques intended for a large-scale production. More importantly, PVDF/PVDF-TrFE binary blends supplemented with BaTiO3 are expected to exhibit superior d33 compared to conventional neat blends, which could make them highly promising for modern energy harvesting and sensor-related applications.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)

Result continuities

  • Project

    <a href="/en/project/GA19-17457S" target="_blank" >GA19-17457S: Manufacturing and analysis of flexible piezoelectric layers for smart engineering</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    NANOCON 2021 Conference Proceedings - International Conference on Nanomaterials

  • ISBN

    978-80-88365-00-6

  • ISSN

    2694-930X

  • e-ISSN

  • Number of pages

    6

  • Pages from-to

    131-136

  • Publisher name

    Tanger Ltd.

  • Place of publication

    Ostrava

  • Event location

    Brno

  • Event date

    Oct 20, 2021

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article