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Unlocking the potential of chlorophyll-based carbon dots towards water-splitting, white-light LED and encryption applications

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F70883521%3A28610%2F25%3A63594599" target="_blank" >RIV/70883521:28610/25:63594599 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0008622325002210?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0008622325002210?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.carbon.2025.120205" target="_blank" >10.1016/j.carbon.2025.120205</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Unlocking the potential of chlorophyll-based carbon dots towards water-splitting, white-light LED and encryption applications

  • Original language description

    The versatile traits of carbon dots (CD) have positioned them as a compelling subject of study across various burgeoning fields. This work has successfully sourced CD from a porphyrin-containing compound, chlorophyll, which boasts outstanding light-harvesting and energy transfer capabilities. CD with excellent physicochemical properties were synthesized using a low-cost solvothermal method. The optical properties of CD have been harnessed for water-splitting applications with ZnO, resulting in significantly improved current efficiency of the photoanodes. When irradiated with AM1.5 G illumination, ZnO/CD heterojunction provided the highest photocurrent efficiency (0.225 mA/cm2 at 1.23 V vs RHE) as a result of enhanced light absorption across the UV to the visible region and improved interfacial charge transfer kinetics in comparison to the pristine ZnO. Additionally, the nanocomposite prepared of CD and boric acid (BACD) evinced promising naked eye phosphorescence for 10 s with an average phosphorescence lifetime of 1.5 s. The BACD nanocomposite was used as a free-standing thin film phosphor material for white light LED preparation and as an ink for data encryption. The results demonstrate that the acquired CD hold substantial promise for a variety of applications.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20501 - Materials engineering

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Carbon

  • ISSN

    0008-6223

  • e-ISSN

  • Volume of the periodical

    238

  • Issue of the periodical within the volume

    Neuveden

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    11

  • Pages from-to

    nestránkováno

  • UT code for WoS article

    001451373300001

  • EID of the result in the Scopus database

    2-s2.0-105000047982