Spectral shifts and structures of phenol center dot center dot center dot Ar-n clusters

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F86652036%3A_____%2F11%3A00430088" target="_blank" >RIV/86652036:_____/11:00430088 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1039/c0cp01370f" target="_blank" >http://dx.doi.org/10.1039/c0cp01370f</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c0cp01370f" target="_blank" >10.1039/c0cp01370f</a>

Result language

angličtina

Original language name

Spectral shifts and structures of phenol center dot center dot center dot Ar-n clusters

Original language description

A laser spectroscopic investigation of phenol center dot center dot center dot Ar-n (n = 1-6) clusters in the first electronically excited state (S-1) and the cationic ground state (D-0) is reported. Resonance enhanced two-photon ionisation (R2PI) spectra have been recorded for the investigation of the S-1 state. The origins of S-1 <- S-0 (S(1)0(0)) transition of phenol center dot center dot center dot Ar-n (n = 1, 2,4-6) are all red shifted compared to the S(1)0(0) state of the monomer by 33 cm(-1), 67cm(-1), 10 cm(-1), 20 cm(-1), 44 cm(-1), respectively. However, the origin of the phenol center dot center dot center dot Ar-3 cluster is blue shifted by 25 cm(-1). For the investigation of the ionic ground state photoionization efficiency (PIE) and mass-analyzed-threshold ionization (MATI) spectroscopy have been applied. The spectra of phenol center dot center dot center dot Ar-3 and phenol center dot center dot center dot Ar-4 yield values for the ionization energy (IE) of 68 077 +/-

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Physical Chemistry Chemical Physics

ISSN

1463-9076

e-ISSN

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Volume of the periodical

13

Issue of the periodical within the volume

13

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

6077-6084

UT code for WoS article

000288447100072

EID of the result in the Scopus database

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