Utilization of magnetically responsive cereal by-product for organic dye removal
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F86652079%3A_____%2F16%3A00466684" target="_blank" >RIV/86652079:_____/16:00466684 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/16:33161386
Result on the web
<a href="http://dx.doi.org/10.1002/jsfa.7337" target="_blank" >http://dx.doi.org/10.1002/jsfa.7337</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/jsfa.7337" target="_blank" >10.1002/jsfa.7337</a>
Alternative languages
Result language
angličtina
Original language name
Utilization of magnetically responsive cereal by-product for organic dye removal
Original language description
BACKGROUND: Barley straw, an agricultural by-product, can also serve as a low-cost and relatively efficient adsorbent of various harmful compounds. In this case, adsorption of four water-soluble dyes belonging to different dye classes (specifically Bismarck brown Y, representing the azo group; methylene blue, quinone-imine group; safranin O, safranin group; and crystal violet, triphenylmethane group) on native and citric acid-NaOH-modified barley straw, both in magnetic and non-magnetic versions, was studied. nRESULTS: The adsorption was characterized using three adsorption models, namely Langmuir, Freundlich and Sips. To compare the maximum adsorption capacities (q(max)), the Langmuir model was employed. The q(max) values reached 86.5-124.3 mg of dye per g of native non-magnetic straw and 410.8-520.3 mg of dye per g of magnetic chemically modified straw. Performed characterization studies suggested that the substantial increase in q(max) values after chemical modification could be caused by rougher surface of adsorbent (observed by scanning electron microscopy) and by the presence of higher amounts of carboxyl groups (detected by Fourier transform infrared spectroscopy). The adsorption processes followed the pseudo-second-order kinetic model and thermodynamic studies indicated spontaneous and endothermic adsorption. nCONCLUSION: The chemical modification of barley straw led to a significant increase in maximum adsorption capacities for all tested dyes, while magnetic modification substantially facilitated the manipulation with adsorbent.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
GC - Plant growing, crop rotation
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the Science of Food and Agriculture
ISSN
0022-5142
e-ISSN
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Volume of the periodical
96
Issue of the periodical within the volume
6
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
2204-2214
UT code for WoS article
000372524700041
EID of the result in the Scopus database
2-s2.0-84960200505