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317 (0,205s)

Result

Alkynylation of heterocyclic compounds using hypervalent iodine reagent

The alkynylation of various nitrogen- and/or sulphur-containing heterocyclic compounds using hypervalent iodine TMS-EBX by utilization of tertiary amines under mild conditions is described. The developed metal-free methodology furnishes the ...

CC - Organická chemie

  • 2015
  • Jx
  • Link
Result

Alkynylation of graphene via the Sonogashira C-C cross-coupling reaction on fluorographene

We report successful grafting of alkynyl groups onto graphene via the Sonogashira reaction between fluorographene and terminal alkynes. Theoretical calculations revealed that fluorographene can efficiently bind and oxidize the palladium cata...

Physical chemistry

  • 2019
  • Jimp
  • Link
Result

[2+2+2]-Cocyclotrimerization of 6-Alkynyl-7-benzylpurines with alpha,omega-Diynes

6-Alkynyl-7-benzylpurines were prepared by the Sonogashira reaction from 6-chloro-7-benzylpurines and terminal alkynes. The prepared alkynylpurines were cyclotrimerized with various 1,6-diynes in the presence of Ni(cod)2/2PPh3 catalytic syst...

CC - Organická chemie

  • 2010
  • Jx
Result

Imidazole-Fused Enediynes by Selective C5-C4 Alkynylations of 4,5-Dibromoimidazoles

An efficient synthesis of symmetrical 1,2-disubstituted 4,5-dialkynylimidazoles by Sonogashira alkynylation of the corresponding 4,5-dibromo derivatives was developed. Moreover, through a careful tuning of the palladium ligand, unsymmetrical...

Organic chemistry

  • 2019
  • Jimp
  • Link
Result

Upper Rim-Bridged Calix[4]arenes via Cyclization of meta Alkynyl Intermediates with Diphenyl Diselenide

-promoted electrophilic closure. It turns out that the calix[4]arenes give completely...

Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

  • 2024
  • Jimp
  • Link
Result

Electrophilic substitution of 2-substituted vinyltin compounds

Electrophilic substitution of vinyltin compounds was studied.

CA - Anorganická chemie

  • 2002
  • D
Result

An efficient synthesis of cytostatic mono and bis-alkynylpyrimidine derivatives by the Sonogashira cross-coupling reactions of 2,4-diamino-6-iodopyrimidine and 2-amino-4,6-dichloropyrimidine

A series of 6-alkynyl-2,4-diaminopyrimidine derivatives bearing various substituents at alkynyl moiety was prepared by the Sonogashira cross-coupling reaction of 2,4-diamino-6-iodopyrimidine using Pd(pph3)2Cl2 as catalyst. The same ...

CC - Organická chemie

  • 2004
  • Jx
Result

Zjednodušené metody pro funkcionalizaci 3-hexoxythiofenů v poloze 5 a jejich další reakce na alkynyl a vinyl deriváty

Kinetically controlled lithiation of 3-hexoxythiophene in the 5-position allows the synthesis of interesting functionalised building blocks after reaction with N,N-dimethylformamide and iodine....

CC - Organická chemie

  • 2009
  • Jx
Result

2,6-Dihalopurines: Preparation of Magnesiated Purines and their Reaction with Electrophiles.

2,6-Dihalopurines: Preparation of Magnesiated Purines and their Reaction with Electrophiles.

CC - Organická chemie

  • 2005
  • O
Result

Electrophilic polyfluoroalkylating agents based on sulfonate esters

Electrophilic polyfluoroalkylating agents based on sulfonate esters...

CC - Organická chemie

  • 2008
  • Jx
  • 1 - 10 out of 317