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3 (0,052s)

Result

Phosphadicarbaborane analogues of ferrocene: New isomers of [closo-(eta(5)-C5H5)FePC2B8H10]

Thermal isomerisation of the ferraphosphadicarbaborane [1-Cp-closo-1,2,4,5-FePC2B8H10] (1a; Cp = eta(5)-C5H5-) at elevated temperatures (180-350 degreesC) leads to the formation of three new isomeric complexes....

CA - Anorganická chemie

  • 2003
  • Jx
Result

Phosphadicarbaborane analogues of ferrocene: New isomers of [closo-(eta(5)-C5H5)FePC2B8H10].

Thermal isomerisation of the ferraphosphadicarbaborane [1-Cp-closo-1,2,4,5-FePC2B8H10] (1a; Cp = eta(5)-C5H5-) at elevated temperatures (180-350 degreesC) leads to the formation of three new isomeric complexes. These were characterized by mu...

CA - Anorganická chemie

  • 2003
  • Jx
Result

Formation of two isomeric closo-[(eta(5)-C5H5)FePC2B8H10] phosphadicarbaborane analogues of ferrocene via isolable eta(1)-bonded complexes of the [7-{(eta(5)-C5H5)Fe(CO)(2)}-(eta(1)-nido-PC2B8H10)] type.

The reaction of nido-[7,8,9-PC2B8H11] (1) with [{CpFe(CO)(2)}(2)] (Cp = eta(5)-C5H5-) in benzene (reflux, 3 days) gave an eta(1)-bonded complex [7-Fp-(eta(1)-nido-7,8,9,-PC2B8H10)] (2; Fp = CpFe(CO)(2); yield 38%). A similar reaction at elevated temp...

CA - Anorganická chemie

  • 2003
  • Jx
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