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Is 1-hexene epoxidation in TS-1 diffusion limited in different solvents?
of the Weisz modulus for aslab morphology, the 1-hexene epoxidation reaction in TS-1PFG NMR diffusion measurements were carried out to determine the effect of solvent on intracrystalline reactant diffusiv...
CF - Fyzikální chemie a teoretická chemie
- 2006 •
- Jx
Rok uplatnění
Jx - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
Accessibility enhancement of TS-1-based catalysts for improving the epoxidation of plant oil-derived substrates
Ti-pillared TS-1, an epoxide selectivity of up to 93% is achieved, layered conversion to the epoxide of 27%. Mesoporous TS-1 and conventional microporous TS-1 within layered and...
CF - Fyzikální chemie a teoretická chemie
- 2016 •
- Jx •
- Link
Rok uplatnění
Jx - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
Výsledek na webu
Epoxidation of Olefines on TS-1 Catalyst
. The epoxidation rates decrease with carbon chain elongation. The water concentration has relevant role in epoxidations. The rate of epoxidation increases with higher water of suitable solvent we can speed up the epoxi...
CC - Organická chemie
- 2008 •
- D
Rok uplatnění
D - Stať ve sborníku
Selective Oxidation of Citronellol over Titanosilicate Catalysts
titanium silicalite 1 (TS-1), mesoporous TS-1, layered TS-1 and silica-titania pillared TS-1 and also studying the effect of the solvent used. Epoxidation of C...
Physical chemistry
- 2020 •
- Jimp •
- Link
Rok uplatnění
Jimp - Článek v periodiku v databázi Web of Science
Výsledek na webu
Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks
The cross metathesis of 1,2-epoxy-5-hexene (1) with methyl acrylate. Interestingly, the epoxide ring remained unreactive toward this hydrogenation method. The saturated compound resulting from the cross metathesis of 1<...
CC - Organická chemie
- 2015 •
- Jx •
- Link
Rok uplatnění
Jx - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
Výsledek na webu
Synthesis and Characterisation of Hierarchically Structured Titanium Silicalite-1 Zeolites with Large Intracrystalline Macropores
The successful synthesis of hierarchically structured titanium silicalite-1 (TS during the synthesis. Silicon-to-titanium ratio of the macroporous TS-1 samples was successfully tuned from 100 to 44. The hierarchica...
Physical chemistry
- 2019 •
- Jimp •
- Link
Rok uplatnění
Jimp - Článek v periodiku v databázi Web of Science
Výsledek na webu
Nanosponge TS-1: A Fully Crystalline Hierarchical Epoxidation Catalyst
the structure of other layered titanosilicate catalysts (e.g., silica-titania pillared TS-1). Catalytic tests show: i) that nsTS-1 efficiently catalyzes the epoxidation of cyclicEpoxide production by orga...
Physical chemistry
- 2021 •
- Jimp •
- Link
Rok uplatnění
Jimp - Článek v periodiku v databázi Web of Science
Výsledek na webu
Addressing confinement effect in alkenes epoxidation using 'isoreticular' titanosilicate zeolite catalysts
, while their activity and selectivity were compared in the epoxidation of 1-hexene with similar total concentration of Ti sites (0.15-0.17 mmol/g). For both 1-hexene decreased with the micropore size in a...
Physical chemistry
- 2022 •
- Jimp •
- Link
Rok uplatnění
Jimp - Článek v periodiku v databázi Web of Science
Výsledek na webu
Catalytic amination of 1-hexene over zeolites beta and ZSM-5
Catalytic amination of 1-hexene over zeolites beta and ZSM-5...
CI - Průmyslová chemie a chemické inženýrství
- 2005 •
- O
Rok uplatnění
O - Ostatní výsledky
Reaction of supernucleophiles in the presence of titanosilicates as catalysts
This bachelor thesis deals with the catalyzed reaction between hex-1-ene and hydroxylamine. The reaction was predicted based on an analogy with catalyzed epoxidation of alkenes with hydrogen peroxide. MFI structured TS-...
Chemical engineering
- 2020 •
- O •
- Link
Rok uplatnění
O - Ostatní výsledky
Výsledek na webu
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