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131 516 (0,14s)

Result

Itinerant metamagnetic transition in the ferromagnet LuCo3 induced by high field: instability of the 3d-electron subsystem

-induced phase transition at 50 T from a low-spin to a high-spin state. The transition in the occupancies of the Co 3d electronic states. At the same time, some features in the majority <...

Condensed matter physics (including formerly solid state physics, supercond.)

  • 2020
  • Jimp
  • Link
Result

Spin state of LaCoO3: Dependence on CoO6 octahedra geometry

on the GGA+U method. The spin S of the cobalt ion is found to correspond either to theintermediate spin state [(IS), S=1] or to low spin state [(LS), S=0]. The IS state is more stable than the LS...

BM - Fyzika pevných látek a magnetismus

  • 2005
  • Jx
Result

Relativistic effects in spectroscopy and photophysics of heavy-metal complexes illustrated by spin-orbit calculations of [Re(imidazole)(CO)3(phen)]+.

transition metal complexes. By enabling efficient population of the lowest triplet state presenta new photophysical model based on mixed-spin states, illustrated by relativistic spin-orbit TDDFT and MS-CA...

CF - Fyzikální chemie a teoretická chemie

  • 2011
  • Jx
  • Link
Result

Non-covalent control of spin-state in metal-organic complex by positioning on N-doped graphene

different spin states of single molecules. Moreover, we present a method for triggering spin state transitions and tuning the electronic properties of molecules throughHere we demonstrate control over the...

Physical chemistry

  • 2018
  • Jimp
  • Link
Result

Charge transfer, valence, and the metal-insulator transition in Pr0.5Ca0.5CoO3.

evidence that the recently observed simultaneous metal-insulator and spin-state transition in perovskite cobaltite Pr0.5Ca0.5CoO3 is accompanied by a charge transfer between Prand Co cations from 0.5 Pr3+ + Co3.5+...

BM - Fyzika pevných látek a magnetismus

  • 2010
  • Jx
Result

Magnetic control of single transition metal doped MoS2 through H/F chemical decoration

Using density function theory, we study the spin state control of transition metal doped MoS2 through H/F chemical decoration. The results indicate that the ground spin state of single TM (Mn, Fe, and ...

Physical chemistry

  • 2017
  • Jimp
  • Link
Result

Enhanced photodegradation in metal oxide nanowires with Co-doped surfaces under a low magnetic field

of the hydrophilic–hydrophobic transitions at the ZnO surfaces as a result of the diffusion of Co atoms. Due to the controllable spin-dependent density of states (DOS) inducedThe enhancement of photodegradation in...

Condensed matter physics (including formerly solid state physics, supercond.)

  • 2021
  • Jimp
  • Link
Result

Evolution of charge and spin state of transition metals in the LaMn1-xCoxO3 perovskite serie

Charge and spin state evolution of the transition metals in the LaMn1-xCoxO3 Spectroscopy. The high spin of the Mn3+/4+ and Co2+ ions is preserved in the entire solidsolution. Co3+ ions reveal low spin

BM - Fyzika pevných látek a magnetismus

  • 2008
  • Jx
Result

Valence and spin states in perovskites LaCo0.95M0.05O3 (M = Mg, Ga, Ti)

the temperature range up to 900 K. The Co-site substitution does not affect the magnetic transition at 100 K and the onset of massive population of hole carriers at 500 K featuresof Co-site doped and La-site doped samples ...

BM - Fyzika pevných látek a magnetismus

  • 2008
  • Jx
Result

Temperature and pressure-driven spin-state transitions in LaCoO3.

Crystal structure, spin state, and semiconductor-metal transitions of LaCoO3 in the 10?905 K temperature range were studied by neutron diffraction at high pressures nondegenerate magnetic states with different elec...

BM - Fyzika pevných látek a magnetismus

  • 2007
  • Jx
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