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159 932 (0,339s)

Result

The dynamics of band (peak) shape development in capillary zone electrophoresis in light of the linear theory of electromigration

is electromigration dispersion. In this commented review paper, we compare various models of electromigration, try to find points that connect them, and discuss the range of their validity in light of the linear and nonlin...

Analytical chemistry

  • 2019
  • Jimp
  • Link
Result

A nonlinear electrophoretic model for PeakMaster: Part IV. Electromigration dispersion in systems that contain a neutral complex-forming agent and a fully charged analyte. Experimental verification

The complete mathematical model of electromigration dispersion in systems in the previous part of this series of papers (Part III - Theory). The model was implementedin mobility of the analyte and its nonlinear electrom...

CB - Analytická chemie, separace

  • 2012
  • Jx
  • Link
Result

Simul 6: A fast dynamic simulator of electromigration

Simul 6 is a 1D dynamic simulator of electromigration based on the mathematical model of electromigration in free solutions. The model consists of continuity equations for the movement of electrolytes in a separati...

Physical chemistry

  • 2021
  • Jimp
  • Link
Result

A nonlinear electrophoretic model for PeakMaster: Part III. Electromigration dispersion in systems that contain a neutral complex-forming agent and a fully charged analyte. Theory

We introduce a new nonlinear electrophoretic model for complex-forming systems to characterize the electromigration dispersion (EMD) of the analyte zone we define a new parameter, the nonlinear electromigration mobility slo...

CB - Analytická chemie, separace

  • 2012
  • Jx
  • Link
Result

Eigenmobilities in background electrolytes for capillary zone electrophoresis: III. Linear theory of electromigration

A mathematical model of capillary zone electrophoresis (CZE) based on the conception of eigenmobilities...

CF - Fyzikální chemie a teoretická chemie

  • 2004
  • Jx
Result

Electromigration properties of borate buffers as background electrolytes in CZE.

This contribution brings a theoretical and experimental study of these buffers and a comparison of the electromigration properties of BGEs consisting of sodium borate and Tris-borate, by following the symmetry and asymmetry of peaks of a sel...

CB - Analytická chemie, separace

  • 2002
  • D
Result

PeakMaster and Simul - Software tools for mastering electrophoresis

model. An alternate approach is the formulation of the approximate linear model for capillary zone electrophoresis. The nonlinear and linear models of electromigration. Both of them serve for method development in...

Analytical chemistry

  • 2023
  • Jimp
  • Link
Result

Generalized model of electromigration with 1:1 (analyte:selector) complexation stoichiometry: Part I. Theory

The model of electromigration of a multivalent weak acidic/basic/amphoteric. The model provides an extension of the series of models starting with the single-selector model without dissociation by Wren and...

CB - Analytická chemie, separace

  • 2015
  • Jx
  • Link
Result

Mathematical model of electromigration allowing the deviation from electroneutrality

propose a new mathematical model of electromigration considering the high deviation phases is described by various models, of which the Stern-Gouy-Chapman model is still and of any complexity. The mathematical

Physical chemistry

  • 2021
  • Jimp
  • Link
Result

Combining electromigration techniques and mass spectrometry

The lecture deals with combination of electromigration techniques and mass spectrometry, gel and capillary electrohoresis to MALDI, ESI and ICP MS....

CB - Analytická chemie, separace

  • 2011
  • O
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