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Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host-guest complexation with gamma-cyclodextrin
We report the modification of the 2-ammonio group at halogenated decaborate ions with 2,3-epoxypropane, the product of which reacts readily with nucleophiles to form previously inaccessible coupling of polyhedra with organic molecules and ma...
Inorganic and nuclear chemistry
- 2019 •
- Jimp •
- Link
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Jimp - Článek v periodiku v databázi Web of Science
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Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules, host-guest complexation with γ-cyclodextrin
We report the modification of the 2-ammonio group at halogenated decaborate ions with 2,3-epoxypropane, the product of which reacts readily with nucleophiles to form previously inaccessible coupling of polyhedra with organic molecules and ma...
Inorganic and nuclear chemistry
- 2019 •
- Jimp •
- Link
Rok uplatnění
Jimp - Článek v periodiku v databázi Web of Science
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Recent progress in the development of halogenated building blocks based on closo-decaborate and closo-dodecaborate anions
In this contribution we report on procedures that facilitate easy perhalogenation of basic 10-and12-vertex borane anion. New preparative methods for perhalogenation of the [B10H10]2- ion that produce [B10H10]2- species (X=Cl, Br,I) have bee...
Inorganic and nuclear chemistry
- 2016 •
- O
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O - Ostatní výsledky
Stealth amphiphiles: self-assembly of polyhedral boron clusters
behavior of anionic polyhedral boranes (sodium decaborate, sodium dodecaborate, and it is evident that all the anionic boron clusters form multimolecular aggregates in water of studied clusters spans from a small hydrophil...
CD - Makromolekulární chemie
- 2016 •
- Jx •
- Link
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Jx - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
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Clean-activation of the B–H bond in closo-decahydrodecaborate [B10H10]2− anion via soft-route
Series of closo-decaborate (NH4)2[B10H10] derivatives were prepared by their direct reaction with ligand L (alcohols or nitriles) via an auto-catalyzed reaction with NH4+ present as a counter cation. The reactions were carried out under mild...
Inorganic and nuclear chemistry
- 2020 •
- Jimp •
- Link
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Jimp - Článek v periodiku v databázi Web of Science
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Solvent extraction of radioactive Cs+ by hydroborate anionic extractants of the [1-LB10H9]-type (L = amine or phosphine)
New anion derivatives of the closo-decaborate [B10H10](2-) bearing amine or phosphine groups were tested for the extraction of radioactive cesium cations in acidic of Cs+ by these anions to form neutral compounds which are ...
CA - Anorganická chemie
- 2005 •
- Jx
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Jx - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
Technology for production of 10 and 12 vertex borate
The technology has been verified and it has been shown that the process is suitable for the preparation of sodium dodecarborate and, depending on the mode of reaction, also for the preparation of the decarborate salt and optionally the nidoundeborate...
Inorganic and nuclear chemistry
- 2017 •
- Ztech
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Ztech - Ověřená technologie
Synthesis of bis(diphenylphosphinio)octahydro- closo -decaborates L 2 B 10 H 8 (L=Ph 2 PH) and 1-(diphenylphosphinio)-nonahydro- closo -decaborates(1-) [1-LB 10 H 9 ] - (L=Ph 2 PH, PH 2 P(OH
Annotation not available...
CA - Anorganická chemie
- 1999 •
- Jx
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Jx - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
Polyhalogenated Decaborate and 1-Ammoniododecaborate Ions: An Improved Synthesis with Elemental Halogens, and Physicochemical and Chemical Properties
Currently, the whole area of polyhalogenated polyhedral anions is undergoing a renaissance due to their high stability, the kinetic inertness of the cage B-X (X = F, Cl, Br, I) bonds and facile tuning of the physicochemical properties (stabi...
Inorganic and nuclear chemistry
- 2017 •
- Jimp •
- Link
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Jimp - Článek v periodiku v databázi Web of Science
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B-11-NMR shielding effects in the closo borane series: sensitivity of shifts and their additivity
revealed that the alpha-deshielding effect in the monosubstituted anionic [X-BnHn-1](2 shielding effects in the 9- and 10-vertex anionic series....
Inorganic and nuclear chemistry
- 2017 •
- Jimp •
- Link
Rok uplatnění
Jimp - Článek v periodiku v databázi Web of Science
Výsledek na webu
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