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33 024 (0,107s)

Result

Vibrational spectroscopy of the G...C base pair: Experiment, harmonic and anharmonic calculations, and the nature of the anharmonic couplings

The results of harmonic and anharmonic frequency calculations on a guanine theory. Anharmonic frequencies were obtained by the CC-VSCF method with improved PM3 to gas-phase IR-UV double resonance spectral data. Har...

CF - Fyzikální chemie a teoretická chemie

  • 2005
  • Jx
Result

Anharmonic vibrational frequency calculations for solvated molecules in the B3LYP Kohn?Sham basis set limit

The solvent dependence of harmonic and anharmonic vibrational wavenumbers of water, formaldehyde and formamide was studied using the B3LYP method....

CF - Fyzikální chemie a teoretická chemie

  • 2012
  • Jx
  • Link
Result

Reliable Theoretical Treatment of Molecular Clusters: Counterpoise-Corrected Potential Energy Surface and Anharmonic Vibrational Frequencies of the Water Dimer.

Original scientific paper dealing with Reliable Theoretical Treatment of Molecular Clusters: Counterpoise-Corrected Potential Energy Surface and Anharmonic Vibrational Frequencies of the Water Dimer....

CF - Fyzikální chemie a teoretická chemie

  • 1999
  • Jx
Result

Neutron TAS spin-echo - a handle to anharmonic effects in lattice dynamics.

The combination of two traditional neutron techniques-three-axis spectroscopy and spin-echo spectroscopy-opens access to experimental studies of weak anharmonic effects in lattice dynamics, such at thermal variation of photon frequencies...

BG - Jaderná, atomová a molekulová fyzika, urychlovače

  • 2002
  • Jx
Result

Tuning of dielectric properties of SrTiO3 in the terahertz range

is interpreted in terms of soft-mode hardening due to the anharmonic character of its potential. No additional low-frequency relaxation mode was observed. A weak temperature dependence of the anharmonic coefficients was fo...

BM - Fyzika pevných látek a magnetismus

  • 2011
  • Jx
  • Link
Result

The ab initio assigning of the vibrational probing modes of tryptophan: linear shifting of approximate anharmonic frequencies vs. multiplicative scaling of harmonic frequencies

-dimensional anharmonic Hamiltonians and potential energy functions evaluated by means...

CF - Fyzikální chemie a teoretická chemie

  • 2009
  • Jx
Result

Experimental observation of anharmonic effects in coherent phonon dynamics in diamond

We present a study of coherent optical phonon dynamics in monocrystalline and polycrystalline diamond using transient transmission spectroscopy with few-cycle laser pulses. Besides the oscillations at the fundamental phonon frequency of 40 T...

Optics (including laser optics and quantum optics)

  • 2018
  • Jimp
  • Link
Result

Universal anharmonicity and vibrational anomaly in nuclei.

Universal anharmonicity and vibrational anomaly in nuclei.

BG - Jaderná, atomová a molekulová fyzika, urychlovače

  • 2001
  • Jx
Result

CH Stretching Region: Computational Modeling of Vibrational Optical Activity

to be more sensitive to the basis set and solvent variations than lower-frequency vibrations. For a higher accuracy in frequencies and spectral shapes, anharmonic corrections were necessary. Accurate harmonic and anhar...

BO - Biofyzika

  • 2013
  • Jx
  • Link
Result

Log-anharmonic oscillator and its large-N solution

Anharmonic oscillator is considered using an unusual, logarithmic form of the anharmonicity. The model is shown connected with the more conventional power-law anharmonicity similar to vertical bar x vertical bar(alpha) in t...

Atomic, molecular and chemical physics (physics of atoms and molecules including collision, interaction with radiation, magnetic resonances, Mössbauer effect)

  • 2018
  • Jimp
  • Link
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