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100 808 (0,158s)

Result

Optimization of mixed quantum-classical dynamics: Time-derivative coupling terms and selected couplings

The usage of time-derivative non-adiabatic coupling terms and partially coupled time-dependent equations are investigated to accelerate non-adiabatic dynamics of the results and computational cost...

CF - Fyzikální chemie a teoretická chemie

  • 2009
  • Jx
Result

Calculation of non-adiabatic coupling vectors in a local-orbital basis set

In this paper we analyze the calculation of non-adiabatic coupling vectors in a basis set of local orbitals and derive an expression to calculate them in a practical and computationally efficient way. Some examples of the a...

BM - Fyzika pevných látek a magnetismus

  • 2013
  • Jx
  • Link
Result

On the VB Adiabatic-diabatic Picture of Bonding in CO 2+ .

Simple methods to calculate non-adiabatic coupling elements and to approximately diabatize electronic states of the singlet pí manifold of a classical VB model that the bound character of an adiabatic state is comp...

CF - Fyzikální chemie a teoretická chemie

  • 2001
  • Jx
Result

Non-adiabatic correction for coupled Morse oscillators using Hutson and Howard perturbation theory

BG - Jaderná, atomová a molekulová fyzika, urychlovače

  • 1995
  • Jx
Result

Full quantum study of non-radiative inelastic processes in lithium-helium ion-atom collisions

. Radial non-adiabatic coupling matrix elements between states of the same symmetry are calculated. Quantum non-adiabatic nuclear dynamics is studied by the reprojection method, which takes into account al...

BG - Jaderná, atomová a molekulová fyzika, urychlovače

  • 2015
  • Jx
  • Link
Result

The inverse problem of two-state quantum systems with non-adiabatic static linear coupling

We consider the inverse problem of determining the coupling coefficients in a two-state Schrodinger system. We prove a Lipschitz stability inequality for the zeroth- and first-order coupling terms by finitely many partial lateral me...

Applied mathematics

  • 2021
  • Jimp
  • Link
Result

Non-adiabatic molecular dynamic simulations of opening reaction of molecular junctions

We report non-adiabatic molecular dynamic simulations of the ring opening reaction of diarylethene (DAE) derivative molecules, both free standing and embedded between gold electrodes. Simulations are performed by the surface hopping...

Electrical and electronic engineering

  • 2016
  • Jimp
  • Link
Result

Cis-trans photoisomerization of azobenzene upon excitation to the S-1 state: An ab initio molecular dynamics and QM/MM study

both in gas phase and in solution. Our study is based on ab initio non-adiabatic dynamics simulations with the non-adiabatic effects included via the fewest-switches surfacehopping method with potential-energy sur...

CF - Fyzikální chemie a teoretická chemie

  • 2012
  • D
  • Link
Result

Non adiabatic calometer

Non adiabatic metod on the principle of mixing calorimeter focuses on correction of heat loss . In fact, each part of the heat supplied to the calorimeter system uses to heat its components and part is paid to the surroundings. This...

JN - Stavebnictví

  • 2013
  • Gfunk
  • Link
Result

Adiabatic temperature change from non-adiabatic measurements

A methodology to obtain the adiabatic temperature change from non-adiabatic measurements is presented. The methodology combines measurements of temperature changes. The results for Gadolinium indicate an ability to determin...

BM - Fyzika pevných látek a magnetismus

  • 2016
  • Jx
  • Link
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