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Dinuclear Fe(III) complexes with spin crossover
-III](BPh4)(2), thermally induced spin crossover is observed. The corollary of the systems is that the spin crossover interferes with the magnetic exchange interaction. The overlap of the energy bands of the LL and...
CA - Anorganická chemie
- 2009 •
- Jx
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A variable-temperature Q- and X-band EPR study of spin-crossover iron(III) Schiff base complex
. The first derivative Q- and X-band EPR spectra of spin-crossover iron(III) complex exhibit the presence of the high spin (S = 5/2) and low spin (S = 1/2) iron(III) state. The variable-temperature EPR measurement ...
Physical chemistry
- 2020 •
- Jimp •
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One-dimensional tunable photonic crystals with spin crossover material for the terahertz range
The autors use a spin crossover material as a defect inserted into a periodic structure of alternating layers of glass and air. A single defect mode of this Bragg filter designed for the submillimeter wavelength can be tuned over 15...
BM - Fyzika pevných látek a magnetismus
- 2006 •
- Jx
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A chiral spin crossover metal-organic framework
A chiral metal-organic framework exhibiting spin crossover (SCO) property, [FeII(mptpy)2]EtOH0.2DMF (1solv), has been solvothermally synthesized through spontaneous resolution. It displays remarkable stability and two-step SCO at (T...
CF - Fyzikální chemie a teoretická chemie
- 2014 •
- Jx •
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Homochiral Mn3+ spin-crossover complexes: a structural and spectroscopic study
Structural, magnetic, and spectroscopic data on a Mn3+ spin-crossover complex orthorhombic space group P21212. Complexes 1 and 2 are high-spin, complex 4 undergoes a gradual and complete thermal spin crossover<...
Inorganic and nuclear chemistry
- 2022 •
- Jimp •
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Pressure-induced spin state crossover in layered cobaltite LaSrCoO4
expansion at high pressure are observed, indicative for the pressure induced spin state crossover of Co3+ ions from the mixed low spin – high spin (LS + HS) state at room temperature towards the low spin ...
Condensed matter physics (including formerly solid state physics, supercond.)
- 2019 •
- Jimp •
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Observation of two-step spin transition in iron(ii) 4-amino-1,2,4-triazole based spin crossover nanoparticles
A synthetically controllable two-step spin transition was observed in iron(ii) spin crossover nanoparticles of the dehydrated one-dimensional coordination polymer [Fe(NH(2)trz)(3)]Br-2 (NH(2)trz = 4-amino-1,2,4-triazole) us...
Nano-processes (applications on nano-scale); (biomaterials to be 2.9)
- 2023 •
- Jimp •
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Interplay between spin crossover and exchange interaction in iron(III) complexes
In the dinuclear and polynuclear metal complexes exhibiting the low-spin (LS) to high-spin (HS) transition, the spin-crossover phenomenon interferes with the magnetic exchange interaction. The latter manifests itse...
CA - Anorganická chemie
- 2009 •
- Jx
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Jx - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
Enhancing Magnetic Cooperativity in Fe(II) Triazole-based Spin-crossover Nanoparticles by Pluronic Matrix Confinement
Polymeric one-dimensional (1D) triazole-based Fe(II)spin crossover nanoparticles have been entrapped in pluronic P123 matrix, forming nanorods in which the interaction between host (P123) and guest (Fe(II)complex) promoted high repr...
Physical chemistry
- 2020 •
- Jimp •
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Spin Crossover in Iron(II) Porphyrazine Induced by Noncovalent Interactions Combined with Hybridization of Iron(II) Porphyrazine and Ligand's Orbitals: CASPT2, CCSD(T), and DFT Studies
Spin crossover processes invoked by external stimuli, e.g., temperature on spin crossover is, however, much less explored. To improve understanding of the origin of spin crossover processes driven...
Physical chemistry
- 2019 •
- Jimp •
- Link
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Jimp - Článek v periodiku v databázi Web of Science
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