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Preparation and characterization of metal/polymer structures

Project goals

The interactions between metals and polymers will be studied using complementary analytical techniques on different metal-polymer and metal-polymer-metal systems. The research is of interest from the fundamental point of view and for broad practical utilization of metal coated polymers in analytical chemistry, electronics, food packaging etc. The specimens will be prepared by sputtering or vacuum deposition of 10-100 nm thick layers of different metals Au, Ag, Pd and Pt on various polymers PET, PMMA, PEand PTFE. The structure characterization will be provided using profilometer, TEM, AAS spectroscopy, RBS, ERD). The electrical resistance and magnetic properties will be measured. Nanointendenter device will be used for the determination of the layers adhesion. The layer morphology will be studied using AFM and SEM. Ion implantation and ion assisted mixing of metal particles and polymer structure will be used for composite preparation. For mobility and diffusion study of metals in polymer substrate RBS, XPS will be used.

Keywords

metal/polymerinterfacemetallizedpolymersplasmamodificationpolymers

Public support

  • Provider

    Czech Science Foundation

  • Programme

    Standard projects

  • Call for proposals

    Standardní projekty 12 (SGA02009GA-ST)

  • Main participants

  • Contest type

    VS - Public tender

  • Contract ID

    106-09-0125

Alternative language

  • Project name in Czech

    Příprava a vlastnosti struktur kov/polymer

  • Annotation in Czech

    Interakce kovu s polymery bude studována komplementárními analytickými metodami na různých systémech kov-polymer a kov-polymer-kov. Tento výzkum je zajímavý z fundamentálního i praktického hlediska, neboť takové struktury nacházejí široké využití od analytické chemie a elektroniky až po obalovou techniku. Vzorky budou připraveny naprašováním a vakuovým napařováním vrstev kovů Au, Ag, Pd a Pt o tlouštkách 10-100 nm na vybrané polymery PET, PMMA, PE a PTFE. Deponované struktury budou charakterizovány různými metodami (profilometer, TEM, AAS spektroskopie, RBS, ERD), bude meřen jejich elektrický odpor a  magnetické vlastnosti. Adhese vrstev a jejich tvrdost bude stanovena nanoindentorem. Povrchová morfologie vrstev bude sledována mikroskopicky (AFM, SEM).Iontová implantace a ionty stimulovaný mixing polymeru s kovovými částicemi budou použity k příprave kompozitů. Pohyblivost a difúze atomu kovů v polymerech bude sledována metodami RBS a XPS. Bude studován vliv ozáření polymerního substrátu v plasmatu aUV na kvalitu rozhraní polymer/kov.

Scientific branches

  • R&D category

    ZV - Basic research

  • CEP classification - main branch

    JJ - Other materials

  • CEP - secondary branch

    BG - Nuclear, atomic and molecular physics, accelerators

  • CEP - another secondary branch

    JI - Composite materials

  • 10304 - Nuclear physics
    20502 - Paper and wood
    20503 - Textiles; including synthetic dyes, colours, fibres (nanoscale materials to be 2.10; biomaterials to be 2.9)
    20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)
    21001 - Nano-materials (production and properties)
    21002 - Nano-processes (applications on nano-scale); (biomaterials to be 2.9)

Completed project evaluation

  • Provider evaluation

    V - Vynikající výsledky projektu (s mezinárodním významem atd.)

  • Project results evaluation

    In frame of the project, many interesting results from the field of fabrication and characterization of metal/polymer structures and interaction of ions with solid matter were described. The goals of the projects were fulfilled. Publication outcomes consist of more than 40 papers in impacted journals and several book chapters. The results are potentially applicable. Panel evaluation - excellent.

Solution timeline

  • Realization period - beginning

    Jan 1, 2009

  • Realization period - end

    Dec 31, 2013

  • Project status

    U - Finished project

  • Latest support payment

    Jun 6, 2013

Data delivery to CEP

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

  • Data delivery code

    CEP14-GA0-GA-U/01:1

  • Data delivery date

    Jul 1, 2014

Finance

  • Total approved costs

    5,700 thou. CZK

  • Public financial support

    5,700 thou. CZK

  • Other public sources

    0 thou. CZK

  • Non public and foreign sources

    0 thou. CZK

Basic information

Recognised costs

5 700 CZK thou.

Public support

5 700 CZK thou.

100%


Provider

Czech Science Foundation

CEP

JJ - Other materials

Solution period

01. 01. 2009 - 31. 12. 2013