P,C,P-pincer complexes of p-block elements: from coordination to function.
Public support
Provider
Czech Science Foundation
Programme
Standard projects
Call for proposals
SGA0202600001
Main participants
Univerzita Pardubice / Fakulta chemicko-technologická
Contest type
VS - Public tender
Contract ID
26-20957S
Alternative language
Project name in Czech
P,C,P-pincer complexes of p-block elements: from coordination to function.
Annotation in Czech
This project aims to introduce C-monoanionic P,C,P-pincer ligands into the chemistry of Group 13 and 14 elements (i.e. Al, Ga, In, Ge, Sn and Pb). This would represent their first application in the p-block and would open an entirely new playground in the field of main group elements. The initial goals include the development of efficient synthetic protocols along with the examination of their limits. A detailed structural study with an emphasis on the description of phosphorus-central atom interactions and their influence on complexes properties will be performed from both experimental and theoretical points of view. The oxidation of P-functions will allow switching of the donor-set to O,C,O-, S,C,S- or Se,C,Se-pincers, thereby enriching bonding capabilities of this ligand class. The investigation of Group 13 and 14 hydrides regarding their utilization in hydrometallations and activation of unsaturated organic molecules, carbon dioxide or carbon disulfide represents the second main target. The most promising stoichiometric processes will finally be investigated on a catalytic mode.
Scientific branches
R&D category
ZV - Basic research
OECD FORD - main branch
10402 - Inorganic and nuclear chemistry
OECD FORD - secondary branch
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OECD FORD - another secondary branch
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CEP - equivalent branches <br>(according to the <a href="http://www.vyzkum.cz/storage/att/E6EF7938F0E854BAE520AC119FB22E8D/Prevodnik_oboru_Frascati.pdf">converter</a>)
CA - Inorganic chemistry<br>CH - Nuclear and quantum chemistry, photo chemistry
Solution timeline
Realization period - beginning
Jan 1, 2026
Realization period - end
Dec 31, 2028
Project status
Z - Beginning multi-year project
Latest support payment
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Data delivery to CEP
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data delivery code
CEP26-GA0-GA-R
Data delivery date
May 26, 2026
Finance
Total approved costs
6,435 thou. CZK
Public financial support
6,435 thou. CZK
Other public sources
0 thou. CZK
Non public and foreign sources
0 thou. CZK