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Self-assembly processes playing a decisive role in the enhanced effectiveness of solar cells

Public support

  • Provider

    Czech Science Foundation

  • Programme

    Standard projects

  • Call for proposals

    SGA0202600001

  • Main participants

    Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská

  • Contest type

    VS - Public tender

  • Contract ID

    26-22190S

Alternative language

  • Project name in Czech

    Self-assembly processes playing a decisive role in the enhanced effectiveness of solar cells

  • Annotation in Czech

    The project explores the pivotal role of self-assembled monolayers (SAMs) in enhancing the performance and stability of solar cells, ultimately focusing on their application as hole-selective layers in perovskite and organic photovoltaic devices. A variety of SAMs, including carbazole-based, phenothiazine-based, and conjugated monolayers, will be thoroughly reviewed and further developed based on theoretical optimization and feedback from targeted microscopic and nanoscopic characterization techniques. New molecular structures, synthetic methodologies, and assembly techniques will be developed. We will exploit the structural variations in anchoring groups, linker chains, and functional head groups, examining their influence on charge distribution, energy alignment, and surface defect density. These parameters, extracted from advanced characterization and DFT calculations, will be fed into a classical semiconductor model equipped with quantum mechanical features. Following validation on real fabricated devices, the model will unravel the role of SAMs in the photovoltaic device.

Scientific branches

  • R&D category

    ZV - Basic research

  • OECD FORD - main branch

    21001 - Nano-materials (production and properties)

  • OECD FORD - secondary branch

    20501 - Materials engineering

  • OECD FORD - another secondary branch

    10403 - Physical chemistry

  • CEP - equivalent branches <br>(according to the <a href="http://www.vyzkum.cz/storage/att/E6EF7938F0E854BAE520AC119FB22E8D/Prevodnik_oboru_Frascati.pdf">converter</a>)

    CF - Physical chemistry and theoretical chemistry<br>JG - Metallurgy, metal materials<br>JJ - Other materials<br>JP - Industrial processes and processing

Solution timeline

  • Realization period - beginning

    Jan 1, 2026

  • Realization period - end

    Dec 31, 2028

  • Project status

    Z - Beginning multi-year project

  • Latest support payment

Data delivery to CEP

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

  • Data delivery code

    CEP26-GA0-GA-R

  • Data delivery date

    May 6, 2026

Finance

  • Total approved costs

    11,738 thou. CZK

  • Public financial support

    11,411 thou. CZK

  • Other public sources

    273 thou. CZK

  • Non public and foreign sources

    54 thou. CZK