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Triggering and probing ultrafast reactions with high-energy photons: Advancing computational methods

Public support

  • Provider

    Czech Science Foundation

  • Programme

    Standard projects

  • Call for proposals

    SGA0202600001

  • Main participants

    Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská

  • Contest type

    VS - Public tender

  • Contract ID

    26-22810S

Alternative language

  • Project name in Czech

    Triggering and probing ultrafast reactions with high-energy photons: Advancing computational methods

  • Annotation in Czech

    Novel light sources such as X-ray free-electron lasers (XFELs) and high-harmonic generation (HHG) offer unprecedented access to ultrafast high-energy processes in radiation chemistry. However, the theory necessary for interpretation lags behind experiments. This project aims to understand, predict, and design ultrafast processes driven by high-energy photons using ab initio simulations. We will develop computational tools for modeling (i) XUV-initiated processes probed by XUV pulses, (ii) X-ray-initiated processes probed by X-ray pulses, and (iii) time-resolved X-ray photoelectron spectroscopy (TR-XPS). Our approach combines advanced electronic structure theory with trajectory-based dynamics to accurately capture core-excited states and charge transfer processes. In close collaboration with experimental teams at XFEL and HHG facilities, we will refine theoretical protocols to interpret and guide experiments. The ultimate goal is to reveal new reaction mechanisms in molecular and condensed-phase systems, bridging photochemistry and radiation chemistry.

Scientific branches

  • R&D category

    ZV - Basic research

  • OECD FORD - main branch

    10301 - Atomic, molecular and chemical physics (physics of atoms and molecules including collision, interaction with radiation, magnetic resonances, Mössbauer effect)

  • OECD FORD - secondary branch

    10403 - Physical chemistry

  • OECD FORD - another secondary branch

  • CEP - equivalent branches <br>(according to the <a href="http://www.vyzkum.cz/storage/att/E6EF7938F0E854BAE520AC119FB22E8D/Prevodnik_oboru_Frascati.pdf">converter</a>)

    BE - Theoretical physics<br>CF - Physical chemistry and theoretical chemistry

Solution timeline

  • Realization period - beginning

    Jan 1, 2026

  • Realization period - end

    Dec 31, 2028

  • Project status

    Z - Beginning multi-year project

  • Latest support payment

Data delivery to CEP

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

  • Data delivery code

    CEP26-GA0-GA-R

  • Data delivery date

    Apr 29, 2026

Finance

  • Total approved costs

    9,998 thou. CZK

  • Public financial support

    9,596 thou. CZK

  • Other public sources

    336 thou. CZK

  • Non public and foreign sources

    66 thou. CZK