Correlation between the standard Gibbs energies of an anion transfer from water to highly hydrophobic ionic liquids and to 1,2-dichloroethane

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11120%2F14%3A43908001" target="_blank" >RIV/00216208:11120/14:43908001 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/14:00424224
Result on the web
<a href="http://dx.doi.org/10.1016/j.jelechem.2013.12.032" target="_blank" >http://dx.doi.org/10.1016/j.jelechem.2013.12.032</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jelechem.2013.12.032" target="_blank" >10.1016/j.jelechem.2013.12.032</a>

Result language
angličtina
Original language name
Correlation between the standard Gibbs energies of an anion transfer from water to highly hydrophobic ionic liquids and to 1,2-dichloroethane
Original language description
Cyclic voltammetry is used to investigate the transfer of several semihydrophobic and hydrophilic anions (F-, Cl-, Br-, I-, NO3-, NO2-, SCN-, BF4-, ClO4-, PF6-) across the polarized interface between an aqueous electrolyte solution and a highly hydrophobic ionic liquid (IL) membrane. Three ILs are examined being composed of the trioctadecylmethylammonium (TOMA+), tridodecylmethylammonium (TDMA+) or tetradodecylammonium (TDA+) cation and the tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (TFPB) anion. The standard Gibbs energies of the anion transfer from water to IL, are evaluated from the voltammetric measurements by applying the classical tetraphenylarsonium-tetraphenylborate hypothesis. Comparison of data for various ILs points to a small systematiceffect of the cationic IL component, which is manifested by somewhat lower values of Gibbs energy for most anions in the presence of TDMA+ or TDA+, indicating their stronger association with the anions. The capillary electrophoresis meas
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Project
<a href="/en/project/GAP206%2F11%2F0707" target="_blank" >GAP206/11/0707: Voltammetric assessment of new ionic liquids for their applications in capillary electrophoresis</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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