Origin of the correlation between the standard Gibbs energies of ion transfer from water to a hydrophobic ionic liquid and to a molecular solvent

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00384568" target="_blank" >RIV/68378271:_____/13:00384568 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/13:00384568
Result on the web
<a href="http://dx.doi.org/10.1016/j.electacta.2012.09.110" target="_blank" >http://dx.doi.org/10.1016/j.electacta.2012.09.110</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2012.09.110" target="_blank" >10.1016/j.electacta.2012.09.110</a>

Result language
angličtina
Original language name
Origin of the correlation between the standard Gibbs energies of ion transfer from water to a hydrophobic ionic liquid and to a molecular solvent
Original language description
Cyclic voltammetry was used to evaluate the standard Gibbs energy of transfer of a series of semi-hydrophobic ions from water to the newly synthesized highly hydrophobic ionic liquid (IL) composed of the tridodecylmethylammonium (TDMA+) cation and the dicarbollylcobaltate (DCC) anion. Results were compared with those reported for the ion transfer to 1,2-dichloroethane (DCE) and to ILs composed of the same cation but a structurally different anion: tetrakis(pentafluorophenyl)borate (TPFPB) or tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (TFPB), and composed of the structurally different (ferrocenylmethyl)dodecyldimethylammonium+ cation (FcMDDA+) and the same anion (TFPB). Dielectric relaxation spectroscopy (DRS) measurements of TDMADCC and TDMATPFPB provided the static (?s) and optical (?) dielectric constants as the low- and high-frequency limits of the complex dielectric permittivity, respectively, as well as the corresponding relaxation times. The observed differences in the dielec
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP206%2F11%2F0707" target="_blank" >GAP206/11/0707: Voltammetric assessment of new ionic liquids for their applications in capillary electrophoresis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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