Use of thiol functionalities for the preparation of porous monolithic structures and modulation of their surface chemistry: A review

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11160%2F19%3A10400652" target="_blank" >RIV/00216208:11160/19:10400652 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=ZEUb7nVGVa" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=ZEUb7nVGVa</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.trac.2019.06.027" target="_blank" >10.1016/j.trac.2019.06.027</a>

Result language
angličtina
Original language name
Use of thiol functionalities for the preparation of porous monolithic structures and modulation of their surface chemistry: A review
Original language description
The state of the art concerning the use of thiol functionalities for the preparation of porous monolithic structures and modulation of their surface chemistry thus enabling a variety of applications is reviewed. The preparation of monoliths with thiol groups is achieved via a single-pot strategy or a parent monolith is prepared followed by post-synthesis modification. Both strategies lead to monolithic structures which applications benefit from the reactivity of thiols. Current thiol functionalized monoliths are formed from silica, synthetic polymers, and hybrid organic-silica materials. Preparation of monolithic columns for chromatography is described as well as the production of heterogeneous catalytic reactors in which the affinity of metal nanoparticles to thiols is used. The application of thiol-ene click reactions for the construction of polymer monoliths is then illustrated. Finally, we discuss the hybrid organic-silica monoliths emphasizing their preparation from polyhedral oligomeric silsesquioxanes. These monoliths are well suited for functionalizations and assist the various click reactions.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry

Project
<a href="/en/project/EF16_019%2F0000841" target="_blank" >EF16_019/0000841: Efficiency and safety improvement of current drugs and nutraceuticals: advanced methods - new challenges</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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