The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F01%3A00107042" target="_blank" >RIV/00216208:11310/01:00107042 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

The cis/trans-isomerism on cobalt(III) complexes with 1,4,8,11-tetraazacyclotetradecane- 1,8-bis(methylphosphonic acid)

Original language description

The X-ray structure determinations show that 1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic) acid H4L forms both cis- and trans-O,O isomeric complexes with Co(III). Orientation of the other donor atoms indicates the formation of cis-O1,O2-trans-N1,N8-cis-O1,N4-[Co(HL)]. The kinetically preferred cis-isomer is easily formed due to the strong hydrogen bond between the neighboring phosphonic acid groups.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

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Volume of the periodical

317

Issue of the periodical within the volume

1-2

Country of publishing house

CH - SWITZERLAND

Number of pages

7

Pages from-to

324-330

UT code for WoS article

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EID of the result in the Scopus database

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