Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F09%3A10000304" target="_blank" >RIV/00216208:11310/09:10000304 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)

Original language description

Two new neutral monoperoxidovanadium(V) complexes [VO(O-2)(L)(pa)]center dot xH(2)O have been synthesized: [VO(O-2)(pic)(pa)]center dot H2O (1) and [VO(O-2)(Hquin)(pa)]center dot 2H(2)O (2) [pic: pyridine-2-carboxylato(1-) or picolinato(1-), Hquin: pyridine-2,3-dicarboxylato(1-) or quinolinato(1-), and pa: picolinamide]. The solid state structures of 1 and 2 feature a typical distorted pentagonal bipyramid coordination polyhedron around the central vanadium atoms. The bidentate anionic ligands are coordinated in two equatorial positions, while the bidentate picolinamide molecule is bound via the aromatic nitrogen and the carboxamide oxygen in one equatorial and one apical position.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

New Journal of Chemistry

ISSN

1144-0546

e-ISSN

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Volume of the periodical

2009

Issue of the periodical within the volume

33

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

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UT code for WoS article

000267728200012

EID of the result in the Scopus database

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