Anion??, lone pair?? and ??? interactions in VO(O2)+ complexes with one dipicolinato(2-)-N,O,O ligand and bearing picolinamidium, nicotinamidium or phenanthrolinium as counterions

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F13%3A00391992" target="_blank" >RIV/61388955:_____/13:00391992 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2013.02.022" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2013.02.022</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2013.02.022" target="_blank" >10.1016/j.molstruc.2013.02.022</a>

Result language
angličtina
Original language name
Anion??, lone pair?? and ??? interactions in VO(O2)+ complexes with one dipicolinato(2-)-N,O,O ligand and bearing picolinamidium, nicotinamidium or phenanthrolinium as counterions
Original language description
From the V2O5single bondH2O2single bondH2dipic?nica/pa/phen?H2O/H2Osingle bondCH3CN reaction systems (H2dipic = dipicolinic acid, nica = nicotinamide, pa = picolinamide, phen = 1,10-phenanthroline), three monoperoxidovanadium(V) complexes have been synthesized and structurally characterized: (Hpa)[VO(O2)(dipic)(H2O)].H2O (1), (Hnica)[VO(O2)(dipic)(H2O)] (2) and (Hphen)[VO(O2)(dipic)(H2O)].H2O (3). The organic counterions in 1?3 are protonated on the aromatic nitrogen atoms, whereas the dipicolinato(2-)(=dipic) ligand adopts a tridentate chelating coordination mode in all three complexes. The NOO donor atoms of dipic occupy the three equatorial positions of the characteristic distorted pentagonal bipyramid around the central vanadium atom. The aqua ligand is located in the apical position trans to the short Vtriple bond; length of mdashO(oxido) bond. In addition to electrostatic cation?anion interactions, the supramolecular architecture of the title complexes is formed by: (i) a networ
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/KAN100400701" target="_blank" >KAN100400701: Hybride nanocomposite materials</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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