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DIASTEREOISOMERIC PROTON-BOUND COMPLEXES OF 1,5-DIAZA-cis-DECALIN IN THE GAS PHASE

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F09%3A10000685" target="_blank" >RIV/00216208:11310/09:10000685 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388963:_____/09:00333357

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    DIASTEREOISOMERIC PROTON-BOUND COMPLEXES OF 1,5-DIAZA-cis-DECALIN IN THE GAS PHASE

  • Original language description

    Diastereoisomeric proton-bound complexes of 1,5-diaza-cis-decalin with butan-2-amine are studied by means of the DFT calculations and mass spectrometry. The homochiral complex is favored by about 4 kJ/mol over the heterochiral complex. For a more looselybound ion-pair complex of the protonated bases 1 and 2 with an iodine counterion the energy difference drops to about 2 kJ/mol.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Collection of czechoslovak chemical communications

  • ISSN

    0010-0765

  • e-ISSN

  • Volume of the periodical

    74

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    12

  • Pages from-to

  • UT code for WoS article

    000265420800001

  • EID of the result in the Scopus database